t-3-Benzyl-r-2,c-6-bis­(4-methoxy­phen­yl)­piperidin-4-one

In the title compound, C(26)H(27)NO(3), the piperidine ring adopts a chair conformation. The two methoxy­phenyl groups attached to the piperidine ring at positions 2 and 6 have equatorial orientations and make a dihedral angle of 87.33 (8)°. The benzyl group at position 3 has an equatorial orientati...

Descripción completa

Detalles Bibliográficos
Autores principales: Jayabharathi, J., Thangamani, A., Balamurugan, S., Thiruvalluvar, A., Linden, A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961717/
https://www.ncbi.nlm.nih.gov/pubmed/21202824
http://dx.doi.org/10.1107/S1600536808015717
_version_ 1782189049274957824
author Jayabharathi, J.
Thangamani, A.
Balamurugan, S.
Thiruvalluvar, A.
Linden, A.
author_facet Jayabharathi, J.
Thangamani, A.
Balamurugan, S.
Thiruvalluvar, A.
Linden, A.
author_sort Jayabharathi, J.
collection PubMed
description In the title compound, C(26)H(27)NO(3), the piperidine ring adopts a chair conformation. The two methoxy­phenyl groups attached to the piperidine ring at positions 2 and 6 have equatorial orientations and make a dihedral angle of 87.33 (8)°. The benzyl group at position 3 has an equatorial orientation. The phenyl ring of the benzyl group makes dihedral angles of 75.60 (9) and 73.69 (9)° with the two benzene rings. Mol­ecules are linked by inter­molecular N—H⋯O and C—H⋯O hydrogen bonds and by C—H⋯π inter­actions.
format Text
id pubmed-2961717
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29617172010-12-30 t-3-Benzyl-r-2,c-6-bis­(4-methoxy­phen­yl)­piperidin-4-one Jayabharathi, J. Thangamani, A. Balamurugan, S. Thiruvalluvar, A. Linden, A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(27)NO(3), the piperidine ring adopts a chair conformation. The two methoxy­phenyl groups attached to the piperidine ring at positions 2 and 6 have equatorial orientations and make a dihedral angle of 87.33 (8)°. The benzyl group at position 3 has an equatorial orientation. The phenyl ring of the benzyl group makes dihedral angles of 75.60 (9) and 73.69 (9)° with the two benzene rings. Mol­ecules are linked by inter­molecular N—H⋯O and C—H⋯O hydrogen bonds and by C—H⋯π inter­actions. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961717/ /pubmed/21202824 http://dx.doi.org/10.1107/S1600536808015717 Text en © Jayabharathi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jayabharathi, J.
Thangamani, A.
Balamurugan, S.
Thiruvalluvar, A.
Linden, A.
t-3-Benzyl-r-2,c-6-bis­(4-methoxy­phen­yl)­piperidin-4-one
title t-3-Benzyl-r-2,c-6-bis­(4-methoxy­phen­yl)­piperidin-4-one
title_full t-3-Benzyl-r-2,c-6-bis­(4-methoxy­phen­yl)­piperidin-4-one
title_fullStr t-3-Benzyl-r-2,c-6-bis­(4-methoxy­phen­yl)­piperidin-4-one
title_full_unstemmed t-3-Benzyl-r-2,c-6-bis­(4-methoxy­phen­yl)­piperidin-4-one
title_short t-3-Benzyl-r-2,c-6-bis­(4-methoxy­phen­yl)­piperidin-4-one
title_sort t-3-benzyl-r-2,c-6-bis­(4-methoxy­phen­yl)­piperidin-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961717/
https://www.ncbi.nlm.nih.gov/pubmed/21202824
http://dx.doi.org/10.1107/S1600536808015717
work_keys_str_mv AT jayabharathij t3benzylr2c6bis4methoxyphenylpiperidin4one
AT thangamania t3benzylr2c6bis4methoxyphenylpiperidin4one
AT balamurugans t3benzylr2c6bis4methoxyphenylpiperidin4one
AT thiruvalluvara t3benzylr2c6bis4methoxyphenylpiperidin4one
AT lindena t3benzylr2c6bis4methoxyphenylpiperidin4one

Ejemplares similares