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Ethyl [(2-hydroxy­phen­yl)(pyridinium-2-ylamino)meth­yl]phospho­nate methanol solvate

In the title compound, C(14)H(17)N(2)O(4)P·CH(3)OH, the planes of the pyridinium-2-ylamino and 2-hydroxy­phenyl groups form a dihedral angle of 75.6 (1)°, with the pyridinium NH group and the 2-hydroxy­phenyl OH group pointing in opposite directions. Three intra­molecular hydrogen bonds are observed...

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Detalles Bibliográficos
Autores principales: Li, Ming-Xia, Zhu, Miao-Li, Lu, Li-Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961726/
https://www.ncbi.nlm.nih.gov/pubmed/21202822
http://dx.doi.org/10.1107/S1600536808015675
Descripción
Sumario:In the title compound, C(14)H(17)N(2)O(4)P·CH(3)OH, the planes of the pyridinium-2-ylamino and 2-hydroxy­phenyl groups form a dihedral angle of 75.6 (1)°, with the pyridinium NH group and the 2-hydroxy­phenyl OH group pointing in opposite directions. Three intra­molecular hydrogen bonds are observed. Two phospho­nate and two methanol mol­ecules are connected by O—H⋯O hydrogen bonds as a centrosymmetric dimeric cluster, and inter­act further with other dimeric clusters via N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds and C—H⋯π inter­actions, resulting in a sheet structure.