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Ethyl [(2-hydroxyphenyl)(pyridinium-2-ylamino)methyl]phosphonate methanol solvate
In the title compound, C(14)H(17)N(2)O(4)P·CH(3)OH, the planes of the pyridinium-2-ylamino and 2-hydroxyphenyl groups form a dihedral angle of 75.6 (1)°, with the pyridinium NH group and the 2-hydroxyphenyl OH group pointing in opposite directions. Three intramolecular hydrogen bonds are observed...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961726/ https://www.ncbi.nlm.nih.gov/pubmed/21202822 http://dx.doi.org/10.1107/S1600536808015675 |
Sumario: | In the title compound, C(14)H(17)N(2)O(4)P·CH(3)OH, the planes of the pyridinium-2-ylamino and 2-hydroxyphenyl groups form a dihedral angle of 75.6 (1)°, with the pyridinium NH group and the 2-hydroxyphenyl OH group pointing in opposite directions. Three intramolecular hydrogen bonds are observed. Two phosphonate and two methanol molecules are connected by O—H⋯O hydrogen bonds as a centrosymmetric dimeric cluster, and interact further with other dimeric clusters via N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds and C—H⋯π interactions, resulting in a sheet structure. |
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