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Ethyl [(2-hydroxyphenyl)(pyridinium-2-ylamino)methyl]phosphonate methanol solvate
In the title compound, C(14)H(17)N(2)O(4)P·CH(3)OH, the planes of the pyridinium-2-ylamino and 2-hydroxyphenyl groups form a dihedral angle of 75.6 (1)°, with the pyridinium NH group and the 2-hydroxyphenyl OH group pointing in opposite directions. Three intramolecular hydrogen bonds are observed...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961726/ https://www.ncbi.nlm.nih.gov/pubmed/21202822 http://dx.doi.org/10.1107/S1600536808015675 |
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author | Li, Ming-Xia Zhu, Miao-Li Lu, Li-Ping |
author_facet | Li, Ming-Xia Zhu, Miao-Li Lu, Li-Ping |
author_sort | Li, Ming-Xia |
collection | PubMed |
description | In the title compound, C(14)H(17)N(2)O(4)P·CH(3)OH, the planes of the pyridinium-2-ylamino and 2-hydroxyphenyl groups form a dihedral angle of 75.6 (1)°, with the pyridinium NH group and the 2-hydroxyphenyl OH group pointing in opposite directions. Three intramolecular hydrogen bonds are observed. Two phosphonate and two methanol molecules are connected by O—H⋯O hydrogen bonds as a centrosymmetric dimeric cluster, and interact further with other dimeric clusters via N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds and C—H⋯π interactions, resulting in a sheet structure. |
format | Text |
id | pubmed-2961726 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29617262010-12-30 Ethyl [(2-hydroxyphenyl)(pyridinium-2-ylamino)methyl]phosphonate methanol solvate Li, Ming-Xia Zhu, Miao-Li Lu, Li-Ping Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(17)N(2)O(4)P·CH(3)OH, the planes of the pyridinium-2-ylamino and 2-hydroxyphenyl groups form a dihedral angle of 75.6 (1)°, with the pyridinium NH group and the 2-hydroxyphenyl OH group pointing in opposite directions. Three intramolecular hydrogen bonds are observed. Two phosphonate and two methanol molecules are connected by O—H⋯O hydrogen bonds as a centrosymmetric dimeric cluster, and interact further with other dimeric clusters via N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds and C—H⋯π interactions, resulting in a sheet structure. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961726/ /pubmed/21202822 http://dx.doi.org/10.1107/S1600536808015675 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Li, Ming-Xia Zhu, Miao-Li Lu, Li-Ping Ethyl [(2-hydroxyphenyl)(pyridinium-2-ylamino)methyl]phosphonate methanol solvate |
title | Ethyl [(2-hydroxyphenyl)(pyridinium-2-ylamino)methyl]phosphonate methanol solvate |
title_full | Ethyl [(2-hydroxyphenyl)(pyridinium-2-ylamino)methyl]phosphonate methanol solvate |
title_fullStr | Ethyl [(2-hydroxyphenyl)(pyridinium-2-ylamino)methyl]phosphonate methanol solvate |
title_full_unstemmed | Ethyl [(2-hydroxyphenyl)(pyridinium-2-ylamino)methyl]phosphonate methanol solvate |
title_short | Ethyl [(2-hydroxyphenyl)(pyridinium-2-ylamino)methyl]phosphonate methanol solvate |
title_sort | ethyl [(2-hydroxyphenyl)(pyridinium-2-ylamino)methyl]phosphonate methanol solvate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961726/ https://www.ncbi.nlm.nih.gov/pubmed/21202822 http://dx.doi.org/10.1107/S1600536808015675 |
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