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Ethyl [(2-hydroxy­phen­yl)(pyridinium-2-ylamino)meth­yl]phospho­nate methanol solvate

In the title compound, C(14)H(17)N(2)O(4)P·CH(3)OH, the planes of the pyridinium-2-ylamino and 2-hydroxy­phenyl groups form a dihedral angle of 75.6 (1)°, with the pyridinium NH group and the 2-hydroxy­phenyl OH group pointing in opposite directions. Three intra­molecular hydrogen bonds are observed...

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Detalles Bibliográficos
Autores principales: Li, Ming-Xia, Zhu, Miao-Li, Lu, Li-Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961726/
https://www.ncbi.nlm.nih.gov/pubmed/21202822
http://dx.doi.org/10.1107/S1600536808015675
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author Li, Ming-Xia
Zhu, Miao-Li
Lu, Li-Ping
author_facet Li, Ming-Xia
Zhu, Miao-Li
Lu, Li-Ping
author_sort Li, Ming-Xia
collection PubMed
description In the title compound, C(14)H(17)N(2)O(4)P·CH(3)OH, the planes of the pyridinium-2-ylamino and 2-hydroxy­phenyl groups form a dihedral angle of 75.6 (1)°, with the pyridinium NH group and the 2-hydroxy­phenyl OH group pointing in opposite directions. Three intra­molecular hydrogen bonds are observed. Two phospho­nate and two methanol mol­ecules are connected by O—H⋯O hydrogen bonds as a centrosymmetric dimeric cluster, and inter­act further with other dimeric clusters via N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds and C—H⋯π inter­actions, resulting in a sheet structure.
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spelling pubmed-29617262010-12-30 Ethyl [(2-hydroxy­phen­yl)(pyridinium-2-ylamino)meth­yl]phospho­nate methanol solvate Li, Ming-Xia Zhu, Miao-Li Lu, Li-Ping Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(17)N(2)O(4)P·CH(3)OH, the planes of the pyridinium-2-ylamino and 2-hydroxy­phenyl groups form a dihedral angle of 75.6 (1)°, with the pyridinium NH group and the 2-hydroxy­phenyl OH group pointing in opposite directions. Three intra­molecular hydrogen bonds are observed. Two phospho­nate and two methanol mol­ecules are connected by O—H⋯O hydrogen bonds as a centrosymmetric dimeric cluster, and inter­act further with other dimeric clusters via N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds and C—H⋯π inter­actions, resulting in a sheet structure. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961726/ /pubmed/21202822 http://dx.doi.org/10.1107/S1600536808015675 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Ming-Xia
Zhu, Miao-Li
Lu, Li-Ping
Ethyl [(2-hydroxy­phen­yl)(pyridinium-2-ylamino)meth­yl]phospho­nate methanol solvate
title Ethyl [(2-hydroxy­phen­yl)(pyridinium-2-ylamino)meth­yl]phospho­nate methanol solvate
title_full Ethyl [(2-hydroxy­phen­yl)(pyridinium-2-ylamino)meth­yl]phospho­nate methanol solvate
title_fullStr Ethyl [(2-hydroxy­phen­yl)(pyridinium-2-ylamino)meth­yl]phospho­nate methanol solvate
title_full_unstemmed Ethyl [(2-hydroxy­phen­yl)(pyridinium-2-ylamino)meth­yl]phospho­nate methanol solvate
title_short Ethyl [(2-hydroxy­phen­yl)(pyridinium-2-ylamino)meth­yl]phospho­nate methanol solvate
title_sort ethyl [(2-hydroxy­phen­yl)(pyridinium-2-ylamino)meth­yl]phospho­nate methanol solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961726/
https://www.ncbi.nlm.nih.gov/pubmed/21202822
http://dx.doi.org/10.1107/S1600536808015675
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