catena-Poly[[tris­(pyridine-κN)copper(II)]-μ-tetra­fluoro­terephthalato-κ(2) O (1):O (4)]

In the title compound, [Cu(C(8)F(4)O(4))(C(5)H(5)N)(3)](n), the Cu(II) atom, lying on a twofold rotation axis, is five-coordinated by two O atoms from two tetra­fluoro­terephthalate ligands and three N atoms from three pyridine ligands in a distorted trigonal-bipyramidal geometry. Adjacent Cu(II) at...

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Detalles Bibliográficos
Autores principales: Zheng, Chang-Ge, Zhang, Jie, Hong, Jian-Quan, Li, Song
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961727/
https://www.ncbi.nlm.nih.gov/pubmed/21202811
http://dx.doi.org/10.1107/S1600536808018977
Descripción
Sumario:In the title compound, [Cu(C(8)F(4)O(4))(C(5)H(5)N)(3)](n), the Cu(II) atom, lying on a twofold rotation axis, is five-coordinated by two O atoms from two tetra­fluoro­terephthalate ligands and three N atoms from three pyridine ligands in a distorted trigonal-bipyramidal geometry. Adjacent Cu(II) atoms are connected via the bridging tetra­fluoro­terephthalate ligands into a one-dimensional chain running along the [101] direction.

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