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5-Chloro-2-methyl-3-phenyl­sulfonyl-1-benzofuran

The title compound, C(15)H(11)ClO(3)S, was prepared by the oxidation of 5-chloro-2-methyl-3-phenyl­sulfanyl-1-benzofuran with 3-chloro­peroxy­benzoic acid. There are two symmetry-independent mol­ecules in the asymmetric unit. The dihedral angles formed by the phenyl ring and the plane of the benzofu...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Son, Byeng Wha, Lee, Uk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961728/
https://www.ncbi.nlm.nih.gov/pubmed/21202832
http://dx.doi.org/10.1107/S1600536808015699
Descripción
Sumario:The title compound, C(15)H(11)ClO(3)S, was prepared by the oxidation of 5-chloro-2-methyl-3-phenyl­sulfanyl-1-benzofuran with 3-chloro­peroxy­benzoic acid. There are two symmetry-independent mol­ecules in the asymmetric unit. The dihedral angles formed by the phenyl ring and the plane of the benzofuran system are 77.80 (8) and 78.34 (8)°. The crystal structure is stabilized by aromatic π–π stacking inter­actions between the furan ring and the benzene rings of neighbouring benzofuran fragments from two symmetry-independent mol­ecules; the centroid–centroid distances within the stacks are 3.689 (4), 3.702 (4), 3.825 (4) and 3.826 (4) Å. Additionally, the stacked mol­ecules exhibit inter- and intra­molecular C—H⋯O inter­actions.