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t-3-Benzyl-r-2,c-6-bis(4-methoxyphenyl)piperidin-4-one oxime
In the title molecule, C(26)H(28)N(2)O(3), the piperidine ring adopts a chair conformation. The two methoxyphenyl groups attached to the piperidine ring at positions 2 and 6 have equatorial orientations, and make a dihedral angle of 80.72 (15)°. The benzyl group at position 3 has an equatorial ori...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961741/ https://www.ncbi.nlm.nih.gov/pubmed/21202850 http://dx.doi.org/10.1107/S1600536808016449 |
Sumario: | In the title molecule, C(26)H(28)N(2)O(3), the piperidine ring adopts a chair conformation. The two methoxyphenyl groups attached to the piperidine ring at positions 2 and 6 have equatorial orientations, and make a dihedral angle of 80.72 (15)°. The benzyl group at position 3 has an equatorial orientation. The oxime group at position 4 has a bisectional orientation. The ring of the benzyl group makes dihedral angles of 64.71 (16) and 84.79 (17)° with the two benzene rings. Molecules are linked by intermolecular N—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds, and C—H⋯π interactions. There is also a C—H⋯O intramolecular interaction. |
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