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t-3-Benzyl-r-2,c-6-bis(4-methoxyphenyl)piperidin-4-one oxime
In the title molecule, C(26)H(28)N(2)O(3), the piperidine ring adopts a chair conformation. The two methoxyphenyl groups attached to the piperidine ring at positions 2 and 6 have equatorial orientations, and make a dihedral angle of 80.72 (15)°. The benzyl group at position 3 has an equatorial ori...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961741/ https://www.ncbi.nlm.nih.gov/pubmed/21202850 http://dx.doi.org/10.1107/S1600536808016449 |
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author | Jayabharathi, J. Thangamani, A. Balamurugan, S. Thiruvalluvar, A. Linden, A. |
author_facet | Jayabharathi, J. Thangamani, A. Balamurugan, S. Thiruvalluvar, A. Linden, A. |
author_sort | Jayabharathi, J. |
collection | PubMed |
description | In the title molecule, C(26)H(28)N(2)O(3), the piperidine ring adopts a chair conformation. The two methoxyphenyl groups attached to the piperidine ring at positions 2 and 6 have equatorial orientations, and make a dihedral angle of 80.72 (15)°. The benzyl group at position 3 has an equatorial orientation. The oxime group at position 4 has a bisectional orientation. The ring of the benzyl group makes dihedral angles of 64.71 (16) and 84.79 (17)° with the two benzene rings. Molecules are linked by intermolecular N—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds, and C—H⋯π interactions. There is also a C—H⋯O intramolecular interaction. |
format | Text |
id | pubmed-2961741 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29617412010-12-30 t-3-Benzyl-r-2,c-6-bis(4-methoxyphenyl)piperidin-4-one oxime Jayabharathi, J. Thangamani, A. Balamurugan, S. Thiruvalluvar, A. Linden, A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(26)H(28)N(2)O(3), the piperidine ring adopts a chair conformation. The two methoxyphenyl groups attached to the piperidine ring at positions 2 and 6 have equatorial orientations, and make a dihedral angle of 80.72 (15)°. The benzyl group at position 3 has an equatorial orientation. The oxime group at position 4 has a bisectional orientation. The ring of the benzyl group makes dihedral angles of 64.71 (16) and 84.79 (17)° with the two benzene rings. Molecules are linked by intermolecular N—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds, and C—H⋯π interactions. There is also a C—H⋯O intramolecular interaction. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961741/ /pubmed/21202850 http://dx.doi.org/10.1107/S1600536808016449 Text en © Jayabharathi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Jayabharathi, J. Thangamani, A. Balamurugan, S. Thiruvalluvar, A. Linden, A. t-3-Benzyl-r-2,c-6-bis(4-methoxyphenyl)piperidin-4-one oxime |
title |
t-3-Benzyl-r-2,c-6-bis(4-methoxyphenyl)piperidin-4-one oxime |
title_full |
t-3-Benzyl-r-2,c-6-bis(4-methoxyphenyl)piperidin-4-one oxime |
title_fullStr |
t-3-Benzyl-r-2,c-6-bis(4-methoxyphenyl)piperidin-4-one oxime |
title_full_unstemmed |
t-3-Benzyl-r-2,c-6-bis(4-methoxyphenyl)piperidin-4-one oxime |
title_short |
t-3-Benzyl-r-2,c-6-bis(4-methoxyphenyl)piperidin-4-one oxime |
title_sort | t-3-benzyl-r-2,c-6-bis(4-methoxyphenyl)piperidin-4-one oxime |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961741/ https://www.ncbi.nlm.nih.gov/pubmed/21202850 http://dx.doi.org/10.1107/S1600536808016449 |
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