Cargando…
3-Pentanone 2,4-dinitrophenylhydrazone
Crystals of the title compound, C(11)H(14)N(4)O(4), were obtained from a condensation reaction of 2,4-dinitrophenylhydrazine and 3-pentanone. In the crystal structure, the molecule, except one methyl group, displays a nearly planar structure. The imino group links to the adjacent nitro group via...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961742/ https://www.ncbi.nlm.nih.gov/pubmed/21202866 http://dx.doi.org/10.1107/S1600536808016887 |
_version_ | 1782189055266521088 |
---|---|
author | Xu, Lu-Feng Shan, Shang Wang, Wen-Long Wang, Shan-Heng |
author_facet | Xu, Lu-Feng Shan, Shang Wang, Wen-Long Wang, Shan-Heng |
author_sort | Xu, Lu-Feng |
collection | PubMed |
description | Crystals of the title compound, C(11)H(14)N(4)O(4), were obtained from a condensation reaction of 2,4-dinitrophenylhydrazine and 3-pentanone. In the crystal structure, the molecule, except one methyl group, displays a nearly planar structure. The imino group links to the adjacent nitro group via intramolecular hydrogen bonding. The partially overlapped arrangement and face-to-face separation of 3.410 (9) Å between parallel benzene rings indicate the existence of π–π stacking between adjacent molecules. The crystal structure also contains weak intermolecular C—H⋯O hydrogen bonding. |
format | Text |
id | pubmed-2961742 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29617422010-12-30 3-Pentanone 2,4-dinitrophenylhydrazone Xu, Lu-Feng Shan, Shang Wang, Wen-Long Wang, Shan-Heng Acta Crystallogr Sect E Struct Rep Online Organic Papers Crystals of the title compound, C(11)H(14)N(4)O(4), were obtained from a condensation reaction of 2,4-dinitrophenylhydrazine and 3-pentanone. In the crystal structure, the molecule, except one methyl group, displays a nearly planar structure. The imino group links to the adjacent nitro group via intramolecular hydrogen bonding. The partially overlapped arrangement and face-to-face separation of 3.410 (9) Å between parallel benzene rings indicate the existence of π–π stacking between adjacent molecules. The crystal structure also contains weak intermolecular C—H⋯O hydrogen bonding. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961742/ /pubmed/21202866 http://dx.doi.org/10.1107/S1600536808016887 Text en © Xu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Xu, Lu-Feng Shan, Shang Wang, Wen-Long Wang, Shan-Heng 3-Pentanone 2,4-dinitrophenylhydrazone |
title | 3-Pentanone 2,4-dinitrophenylhydrazone |
title_full | 3-Pentanone 2,4-dinitrophenylhydrazone |
title_fullStr | 3-Pentanone 2,4-dinitrophenylhydrazone |
title_full_unstemmed | 3-Pentanone 2,4-dinitrophenylhydrazone |
title_short | 3-Pentanone 2,4-dinitrophenylhydrazone |
title_sort | 3-pentanone 2,4-dinitrophenylhydrazone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961742/ https://www.ncbi.nlm.nih.gov/pubmed/21202866 http://dx.doi.org/10.1107/S1600536808016887 |
work_keys_str_mv | AT xulufeng 3pentanone24dinitrophenylhydrazone AT shanshang 3pentanone24dinitrophenylhydrazone AT wangwenlong 3pentanone24dinitrophenylhydrazone AT wangshanheng 3pentanone24dinitrophenylhydrazone |