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3-Penta­none 2,4-dinitro­phenyl­hydrazone

Crystals of the title compound, C(11)H(14)N(4)O(4), were obtained from a condensation reaction of 2,4-dinitro­phenyl­hydrazine and 3-penta­none. In the crystal structure, the mol­ecule, except one methyl group, displays a nearly planar structure. The imino group links to the adjacent nitro group via...

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Detalles Bibliográficos
Autores principales: Xu, Lu-Feng, Shan, Shang, Wang, Wen-Long, Wang, Shan-Heng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961742/
https://www.ncbi.nlm.nih.gov/pubmed/21202866
http://dx.doi.org/10.1107/S1600536808016887
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author Xu, Lu-Feng
Shan, Shang
Wang, Wen-Long
Wang, Shan-Heng
author_facet Xu, Lu-Feng
Shan, Shang
Wang, Wen-Long
Wang, Shan-Heng
author_sort Xu, Lu-Feng
collection PubMed
description Crystals of the title compound, C(11)H(14)N(4)O(4), were obtained from a condensation reaction of 2,4-dinitro­phenyl­hydrazine and 3-penta­none. In the crystal structure, the mol­ecule, except one methyl group, displays a nearly planar structure. The imino group links to the adjacent nitro group via intra­molecular hydrogen bonding. The partially overlapped arrangement and face-to-face separation of 3.410 (9) Å between parallel benzene rings indicate the existence of π–π stacking between adjacent mol­ecules. The crystal structure also contains weak inter­molecular C—H⋯O hydrogen bonding.
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spelling pubmed-29617422010-12-30 3-Penta­none 2,4-dinitro­phenyl­hydrazone Xu, Lu-Feng Shan, Shang Wang, Wen-Long Wang, Shan-Heng Acta Crystallogr Sect E Struct Rep Online Organic Papers Crystals of the title compound, C(11)H(14)N(4)O(4), were obtained from a condensation reaction of 2,4-dinitro­phenyl­hydrazine and 3-penta­none. In the crystal structure, the mol­ecule, except one methyl group, displays a nearly planar structure. The imino group links to the adjacent nitro group via intra­molecular hydrogen bonding. The partially overlapped arrangement and face-to-face separation of 3.410 (9) Å between parallel benzene rings indicate the existence of π–π stacking between adjacent mol­ecules. The crystal structure also contains weak inter­molecular C—H⋯O hydrogen bonding. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961742/ /pubmed/21202866 http://dx.doi.org/10.1107/S1600536808016887 Text en © Xu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Xu, Lu-Feng
Shan, Shang
Wang, Wen-Long
Wang, Shan-Heng
3-Penta­none 2,4-dinitro­phenyl­hydrazone
title 3-Penta­none 2,4-dinitro­phenyl­hydrazone
title_full 3-Penta­none 2,4-dinitro­phenyl­hydrazone
title_fullStr 3-Penta­none 2,4-dinitro­phenyl­hydrazone
title_full_unstemmed 3-Penta­none 2,4-dinitro­phenyl­hydrazone
title_short 3-Penta­none 2,4-dinitro­phenyl­hydrazone
title_sort 3-penta­none 2,4-dinitro­phenyl­hydrazone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961742/
https://www.ncbi.nlm.nih.gov/pubmed/21202866
http://dx.doi.org/10.1107/S1600536808016887
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