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(E)-1-(3-Methoxy­phen­yl)ethanone 4-nitro­phenyl­hydrazone

Crystals of the title compound, C(15)H(15)N(3)O(3), were obtained from a condensation reaction of 4-nitro­phenyl­hydrazine and 3-methoxy­acetophenone. In the crystal structure, the methoxy­phenyl ring is twisted slightly with respect to the nitro­phenyl­hydrazine plane, making a dihedral angle of 14...

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Detalles Bibliográficos
Autores principales: Fan, Zheng, Shan, Shang, Wang, Shan-Heng, Wang, Wen-Long
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961743/
https://www.ncbi.nlm.nih.gov/pubmed/21202963
http://dx.doi.org/10.1107/S1600536808018618
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author Fan, Zheng
Shan, Shang
Wang, Shan-Heng
Wang, Wen-Long
author_facet Fan, Zheng
Shan, Shang
Wang, Shan-Heng
Wang, Wen-Long
author_sort Fan, Zheng
collection PubMed
description Crystals of the title compound, C(15)H(15)N(3)O(3), were obtained from a condensation reaction of 4-nitro­phenyl­hydrazine and 3-methoxy­acetophenone. In the crystal structure, the methoxy­phenyl ring is twisted slightly with respect to the nitro­phenyl­hydrazine plane, making a dihedral angle of 14.81 (8)°. The nitro and meth­oxy groups are each coplanar with the attached benzene rings. The nitro­phenyl and methoxy­phenyl groups are located on opposite sides of the C=N double bond, indicating an E configuration of the mol­ecule. Adjacent mol­ecules are linked together via N—H⋯O hydrogen bonding, forming chains along the [101] direction.
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spelling pubmed-29617432010-12-30 (E)-1-(3-Methoxy­phen­yl)ethanone 4-nitro­phenyl­hydrazone Fan, Zheng Shan, Shang Wang, Shan-Heng Wang, Wen-Long Acta Crystallogr Sect E Struct Rep Online Organic Papers Crystals of the title compound, C(15)H(15)N(3)O(3), were obtained from a condensation reaction of 4-nitro­phenyl­hydrazine and 3-methoxy­acetophenone. In the crystal structure, the methoxy­phenyl ring is twisted slightly with respect to the nitro­phenyl­hydrazine plane, making a dihedral angle of 14.81 (8)°. The nitro and meth­oxy groups are each coplanar with the attached benzene rings. The nitro­phenyl and methoxy­phenyl groups are located on opposite sides of the C=N double bond, indicating an E configuration of the mol­ecule. Adjacent mol­ecules are linked together via N—H⋯O hydrogen bonding, forming chains along the [101] direction. International Union of Crystallography 2008-06-25 /pmc/articles/PMC2961743/ /pubmed/21202963 http://dx.doi.org/10.1107/S1600536808018618 Text en © Fan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fan, Zheng
Shan, Shang
Wang, Shan-Heng
Wang, Wen-Long
(E)-1-(3-Methoxy­phen­yl)ethanone 4-nitro­phenyl­hydrazone
title (E)-1-(3-Methoxy­phen­yl)ethanone 4-nitro­phenyl­hydrazone
title_full (E)-1-(3-Methoxy­phen­yl)ethanone 4-nitro­phenyl­hydrazone
title_fullStr (E)-1-(3-Methoxy­phen­yl)ethanone 4-nitro­phenyl­hydrazone
title_full_unstemmed (E)-1-(3-Methoxy­phen­yl)ethanone 4-nitro­phenyl­hydrazone
title_short (E)-1-(3-Methoxy­phen­yl)ethanone 4-nitro­phenyl­hydrazone
title_sort (e)-1-(3-methoxy­phen­yl)ethanone 4-nitro­phenyl­hydrazone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961743/
https://www.ncbi.nlm.nih.gov/pubmed/21202963
http://dx.doi.org/10.1107/S1600536808018618
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