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(E)-1-(3-Methoxyphenyl)ethanone 4-nitrophenylhydrazone
Crystals of the title compound, C(15)H(15)N(3)O(3), were obtained from a condensation reaction of 4-nitrophenylhydrazine and 3-methoxyacetophenone. In the crystal structure, the methoxyphenyl ring is twisted slightly with respect to the nitrophenylhydrazine plane, making a dihedral angle of 14...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961743/ https://www.ncbi.nlm.nih.gov/pubmed/21202963 http://dx.doi.org/10.1107/S1600536808018618 |
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author | Fan, Zheng Shan, Shang Wang, Shan-Heng Wang, Wen-Long |
author_facet | Fan, Zheng Shan, Shang Wang, Shan-Heng Wang, Wen-Long |
author_sort | Fan, Zheng |
collection | PubMed |
description | Crystals of the title compound, C(15)H(15)N(3)O(3), were obtained from a condensation reaction of 4-nitrophenylhydrazine and 3-methoxyacetophenone. In the crystal structure, the methoxyphenyl ring is twisted slightly with respect to the nitrophenylhydrazine plane, making a dihedral angle of 14.81 (8)°. The nitro and methoxy groups are each coplanar with the attached benzene rings. The nitrophenyl and methoxyphenyl groups are located on opposite sides of the C=N double bond, indicating an E configuration of the molecule. Adjacent molecules are linked together via N—H⋯O hydrogen bonding, forming chains along the [101] direction. |
format | Text |
id | pubmed-2961743 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29617432010-12-30 (E)-1-(3-Methoxyphenyl)ethanone 4-nitrophenylhydrazone Fan, Zheng Shan, Shang Wang, Shan-Heng Wang, Wen-Long Acta Crystallogr Sect E Struct Rep Online Organic Papers Crystals of the title compound, C(15)H(15)N(3)O(3), were obtained from a condensation reaction of 4-nitrophenylhydrazine and 3-methoxyacetophenone. In the crystal structure, the methoxyphenyl ring is twisted slightly with respect to the nitrophenylhydrazine plane, making a dihedral angle of 14.81 (8)°. The nitro and methoxy groups are each coplanar with the attached benzene rings. The nitrophenyl and methoxyphenyl groups are located on opposite sides of the C=N double bond, indicating an E configuration of the molecule. Adjacent molecules are linked together via N—H⋯O hydrogen bonding, forming chains along the [101] direction. International Union of Crystallography 2008-06-25 /pmc/articles/PMC2961743/ /pubmed/21202963 http://dx.doi.org/10.1107/S1600536808018618 Text en © Fan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fan, Zheng Shan, Shang Wang, Shan-Heng Wang, Wen-Long (E)-1-(3-Methoxyphenyl)ethanone 4-nitrophenylhydrazone |
title | (E)-1-(3-Methoxyphenyl)ethanone 4-nitrophenylhydrazone |
title_full | (E)-1-(3-Methoxyphenyl)ethanone 4-nitrophenylhydrazone |
title_fullStr | (E)-1-(3-Methoxyphenyl)ethanone 4-nitrophenylhydrazone |
title_full_unstemmed | (E)-1-(3-Methoxyphenyl)ethanone 4-nitrophenylhydrazone |
title_short | (E)-1-(3-Methoxyphenyl)ethanone 4-nitrophenylhydrazone |
title_sort | (e)-1-(3-methoxyphenyl)ethanone 4-nitrophenylhydrazone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961743/ https://www.ncbi.nlm.nih.gov/pubmed/21202963 http://dx.doi.org/10.1107/S1600536808018618 |
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