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[(1S,2S,3R,4R)-3-Hydr­oxy-4,7,7-tri­methyl­bicyclo­[2.2.1]heptan-2-yl]methyl[(E)-3-(trimethyl­silyl)prop-2-enyl]selen­onium bromide

The title compound, a seleno­nium bromide, C(17)H(33)OSeSi(+)·Br(−), was obtained from the reaction of enanti­omerically pure 4,7,7-trimethyl-2-methyl­selanylbicyclo­[2.2.1]heptan-3-ol and (3-bromopropen­yl)trimethyl­silane in acetone. Due to the chiral bicyclic substituent, the crystal structure is...

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Detalles Bibliográficos
Autores principales: Wang, Hai-Yang, Zhang, Qiang, Li, Yi-Zhi, Gui, Yuan, Huang, Zhi-Zhen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961745/
https://www.ncbi.nlm.nih.gov/pubmed/21202880
http://dx.doi.org/10.1107/S1600536808016863
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author Wang, Hai-Yang
Zhang, Qiang
Li, Yi-Zhi
Gui, Yuan
Huang, Zhi-Zhen
author_facet Wang, Hai-Yang
Zhang, Qiang
Li, Yi-Zhi
Gui, Yuan
Huang, Zhi-Zhen
author_sort Wang, Hai-Yang
collection PubMed
description The title compound, a seleno­nium bromide, C(17)H(33)OSeSi(+)·Br(−), was obtained from the reaction of enanti­omerically pure 4,7,7-trimethyl-2-methyl­selanylbicyclo­[2.2.1]heptan-3-ol and (3-bromopropen­yl)trimethyl­silane in acetone. Due to the chiral bicyclic substituent, the crystal structure is not centrosymmetric and has no symmetry plane, with four chiral C atoms in the cation. The asymmetric unit contains one seleno­nium cation and one bromide anion. C–H⋯Br and O–H⋯Br hydrogen bonds link the ions, forming a one-dimensional R-helical chain-like supra­molecular structure.
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spelling pubmed-29617452010-12-30 [(1S,2S,3R,4R)-3-Hydr­oxy-4,7,7-tri­methyl­bicyclo­[2.2.1]heptan-2-yl]methyl[(E)-3-(trimethyl­silyl)prop-2-enyl]selen­onium bromide Wang, Hai-Yang Zhang, Qiang Li, Yi-Zhi Gui, Yuan Huang, Zhi-Zhen Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, a seleno­nium bromide, C(17)H(33)OSeSi(+)·Br(−), was obtained from the reaction of enanti­omerically pure 4,7,7-trimethyl-2-methyl­selanylbicyclo­[2.2.1]heptan-3-ol and (3-bromopropen­yl)trimethyl­silane in acetone. Due to the chiral bicyclic substituent, the crystal structure is not centrosymmetric and has no symmetry plane, with four chiral C atoms in the cation. The asymmetric unit contains one seleno­nium cation and one bromide anion. C–H⋯Br and O–H⋯Br hydrogen bonds link the ions, forming a one-dimensional R-helical chain-like supra­molecular structure. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961745/ /pubmed/21202880 http://dx.doi.org/10.1107/S1600536808016863 Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Hai-Yang
Zhang, Qiang
Li, Yi-Zhi
Gui, Yuan
Huang, Zhi-Zhen
[(1S,2S,3R,4R)-3-Hydr­oxy-4,7,7-tri­methyl­bicyclo­[2.2.1]heptan-2-yl]methyl[(E)-3-(trimethyl­silyl)prop-2-enyl]selen­onium bromide
title [(1S,2S,3R,4R)-3-Hydr­oxy-4,7,7-tri­methyl­bicyclo­[2.2.1]heptan-2-yl]methyl[(E)-3-(trimethyl­silyl)prop-2-enyl]selen­onium bromide
title_full [(1S,2S,3R,4R)-3-Hydr­oxy-4,7,7-tri­methyl­bicyclo­[2.2.1]heptan-2-yl]methyl[(E)-3-(trimethyl­silyl)prop-2-enyl]selen­onium bromide
title_fullStr [(1S,2S,3R,4R)-3-Hydr­oxy-4,7,7-tri­methyl­bicyclo­[2.2.1]heptan-2-yl]methyl[(E)-3-(trimethyl­silyl)prop-2-enyl]selen­onium bromide
title_full_unstemmed [(1S,2S,3R,4R)-3-Hydr­oxy-4,7,7-tri­methyl­bicyclo­[2.2.1]heptan-2-yl]methyl[(E)-3-(trimethyl­silyl)prop-2-enyl]selen­onium bromide
title_short [(1S,2S,3R,4R)-3-Hydr­oxy-4,7,7-tri­methyl­bicyclo­[2.2.1]heptan-2-yl]methyl[(E)-3-(trimethyl­silyl)prop-2-enyl]selen­onium bromide
title_sort [(1s,2s,3r,4r)-3-hydr­oxy-4,7,7-tri­methyl­bicyclo­[2.2.1]heptan-2-yl]methyl[(e)-3-(trimethyl­silyl)prop-2-enyl]selen­onium bromide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961745/
https://www.ncbi.nlm.nih.gov/pubmed/21202880
http://dx.doi.org/10.1107/S1600536808016863
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