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[(1S,2S,3R,4R)-3-Hydroxy-4,7,7-trimethylbicyclo[2.2.1]heptan-2-yl]methyl[(E)-3-(trimethylsilyl)prop-2-enyl]selenonium bromide
The title compound, a selenonium bromide, C(17)H(33)OSeSi(+)·Br(−), was obtained from the reaction of enantiomerically pure 4,7,7-trimethyl-2-methylselanylbicyclo[2.2.1]heptan-3-ol and (3-bromopropenyl)trimethylsilane in acetone. Due to the chiral bicyclic substituent, the crystal structure is...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961745/ https://www.ncbi.nlm.nih.gov/pubmed/21202880 http://dx.doi.org/10.1107/S1600536808016863 |
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author | Wang, Hai-Yang Zhang, Qiang Li, Yi-Zhi Gui, Yuan Huang, Zhi-Zhen |
author_facet | Wang, Hai-Yang Zhang, Qiang Li, Yi-Zhi Gui, Yuan Huang, Zhi-Zhen |
author_sort | Wang, Hai-Yang |
collection | PubMed |
description | The title compound, a selenonium bromide, C(17)H(33)OSeSi(+)·Br(−), was obtained from the reaction of enantiomerically pure 4,7,7-trimethyl-2-methylselanylbicyclo[2.2.1]heptan-3-ol and (3-bromopropenyl)trimethylsilane in acetone. Due to the chiral bicyclic substituent, the crystal structure is not centrosymmetric and has no symmetry plane, with four chiral C atoms in the cation. The asymmetric unit contains one selenonium cation and one bromide anion. C–H⋯Br and O–H⋯Br hydrogen bonds link the ions, forming a one-dimensional R-helical chain-like supramolecular structure. |
format | Text |
id | pubmed-2961745 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29617452010-12-30 [(1S,2S,3R,4R)-3-Hydroxy-4,7,7-trimethylbicyclo[2.2.1]heptan-2-yl]methyl[(E)-3-(trimethylsilyl)prop-2-enyl]selenonium bromide Wang, Hai-Yang Zhang, Qiang Li, Yi-Zhi Gui, Yuan Huang, Zhi-Zhen Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, a selenonium bromide, C(17)H(33)OSeSi(+)·Br(−), was obtained from the reaction of enantiomerically pure 4,7,7-trimethyl-2-methylselanylbicyclo[2.2.1]heptan-3-ol and (3-bromopropenyl)trimethylsilane in acetone. Due to the chiral bicyclic substituent, the crystal structure is not centrosymmetric and has no symmetry plane, with four chiral C atoms in the cation. The asymmetric unit contains one selenonium cation and one bromide anion. C–H⋯Br and O–H⋯Br hydrogen bonds link the ions, forming a one-dimensional R-helical chain-like supramolecular structure. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961745/ /pubmed/21202880 http://dx.doi.org/10.1107/S1600536808016863 Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Wang, Hai-Yang Zhang, Qiang Li, Yi-Zhi Gui, Yuan Huang, Zhi-Zhen [(1S,2S,3R,4R)-3-Hydroxy-4,7,7-trimethylbicyclo[2.2.1]heptan-2-yl]methyl[(E)-3-(trimethylsilyl)prop-2-enyl]selenonium bromide |
title | [(1S,2S,3R,4R)-3-Hydroxy-4,7,7-trimethylbicyclo[2.2.1]heptan-2-yl]methyl[(E)-3-(trimethylsilyl)prop-2-enyl]selenonium bromide |
title_full | [(1S,2S,3R,4R)-3-Hydroxy-4,7,7-trimethylbicyclo[2.2.1]heptan-2-yl]methyl[(E)-3-(trimethylsilyl)prop-2-enyl]selenonium bromide |
title_fullStr | [(1S,2S,3R,4R)-3-Hydroxy-4,7,7-trimethylbicyclo[2.2.1]heptan-2-yl]methyl[(E)-3-(trimethylsilyl)prop-2-enyl]selenonium bromide |
title_full_unstemmed | [(1S,2S,3R,4R)-3-Hydroxy-4,7,7-trimethylbicyclo[2.2.1]heptan-2-yl]methyl[(E)-3-(trimethylsilyl)prop-2-enyl]selenonium bromide |
title_short | [(1S,2S,3R,4R)-3-Hydroxy-4,7,7-trimethylbicyclo[2.2.1]heptan-2-yl]methyl[(E)-3-(trimethylsilyl)prop-2-enyl]selenonium bromide |
title_sort | [(1s,2s,3r,4r)-3-hydroxy-4,7,7-trimethylbicyclo[2.2.1]heptan-2-yl]methyl[(e)-3-(trimethylsilyl)prop-2-enyl]selenonium bromide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961745/ https://www.ncbi.nlm.nih.gov/pubmed/21202880 http://dx.doi.org/10.1107/S1600536808016863 |
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