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cis-Aquadichlorido[pyrimidin-2(1H)-one-κN (3)]copper(II)
In the title compound, [CuCl(2)(C(4)H(4)N(2)O)(H(2)O)], the Cu(II) cation is coordinated by two chloride anions, one pyrimidin-2-one N atom and one water molecule, giving a slightly distorted square-planar geometry. In the crystal structure, the pyrimidin-2-one rings stack along the b axis, with an...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961748/ https://www.ncbi.nlm.nih.gov/pubmed/21202815 http://dx.doi.org/10.1107/S1600536808018771 |
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author | Kurawa, Mukhtar A. Adams, Christopher J. Orpen, A. Guy |
author_facet | Kurawa, Mukhtar A. Adams, Christopher J. Orpen, A. Guy |
author_sort | Kurawa, Mukhtar A. |
collection | PubMed |
description | In the title compound, [CuCl(2)(C(4)H(4)N(2)O)(H(2)O)], the Cu(II) cation is coordinated by two chloride anions, one pyrimidin-2-one N atom and one water molecule, giving a slightly distorted square-planar geometry. In the crystal structure, the pyrimidin-2-one rings stack along the b axis, with an interplanar distance of 3.306 Å, as do the copper coordination planes (interplanar spacing = 2.998 Å). The coordination around the Jahn–Teller-distorted Cu(II) ion is completed by long Cu⋯O [3.014 (5) Å] and Cu⋯Cl [3.0194 (15) Å] interactions with adjacent molecules involved in this stacking. Several N—H⋯Cl, O—H⋯Cl and O—H⋯O intermolecular hydrogen bonds form a polar three-dimensional network. |
format | Text |
id | pubmed-2961748 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29617482010-12-30 cis-Aquadichlorido[pyrimidin-2(1H)-one-κN (3)]copper(II) Kurawa, Mukhtar A. Adams, Christopher J. Orpen, A. Guy Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CuCl(2)(C(4)H(4)N(2)O)(H(2)O)], the Cu(II) cation is coordinated by two chloride anions, one pyrimidin-2-one N atom and one water molecule, giving a slightly distorted square-planar geometry. In the crystal structure, the pyrimidin-2-one rings stack along the b axis, with an interplanar distance of 3.306 Å, as do the copper coordination planes (interplanar spacing = 2.998 Å). The coordination around the Jahn–Teller-distorted Cu(II) ion is completed by long Cu⋯O [3.014 (5) Å] and Cu⋯Cl [3.0194 (15) Å] interactions with adjacent molecules involved in this stacking. Several N—H⋯Cl, O—H⋯Cl and O—H⋯O intermolecular hydrogen bonds form a polar three-dimensional network. International Union of Crystallography 2008-06-28 /pmc/articles/PMC2961748/ /pubmed/21202815 http://dx.doi.org/10.1107/S1600536808018771 Text en © Kurawa et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kurawa, Mukhtar A. Adams, Christopher J. Orpen, A. Guy cis-Aquadichlorido[pyrimidin-2(1H)-one-κN (3)]copper(II) |
title |
cis-Aquadichlorido[pyrimidin-2(1H)-one-κN
(3)]copper(II) |
title_full |
cis-Aquadichlorido[pyrimidin-2(1H)-one-κN
(3)]copper(II) |
title_fullStr |
cis-Aquadichlorido[pyrimidin-2(1H)-one-κN
(3)]copper(II) |
title_full_unstemmed |
cis-Aquadichlorido[pyrimidin-2(1H)-one-κN
(3)]copper(II) |
title_short |
cis-Aquadichlorido[pyrimidin-2(1H)-one-κN
(3)]copper(II) |
title_sort | cis-aquadichlorido[pyrimidin-2(1h)-one-κn
(3)]copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961748/ https://www.ncbi.nlm.nih.gov/pubmed/21202815 http://dx.doi.org/10.1107/S1600536808018771 |
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