Cargando…
2-[(E)-(5-Amino-2,3-diphenylquinoxalin-6-yl)iminomethyl]-4-bromophenol
The title compound, C(27)H(19)BrN(4)O, is a mono-anil Schiff base ligand. Three intramolecular O—H⋯N and N—H⋯N hydrogen bonds involving the hydroxy and amino groups generate S(6) and S(5) ring motifs, respectively. In the crystal structure, weak intermolecular N—H⋯O and C—H⋯O hydrogen bonds toget...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961755/ https://www.ncbi.nlm.nih.gov/pubmed/21202904 http://dx.doi.org/10.1107/S1600536808017716 |
_version_ | 1782189058343043072 |
---|---|
author | Fun, Hoong-Kun Kia, Reza Raithby, Paul R. |
author_facet | Fun, Hoong-Kun Kia, Reza Raithby, Paul R. |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | The title compound, C(27)H(19)BrN(4)O, is a mono-anil Schiff base ligand. Three intramolecular O—H⋯N and N—H⋯N hydrogen bonds involving the hydroxy and amino groups generate S(6) and S(5) ring motifs, respectively. In the crystal structure, weak intermolecular N—H⋯O and C—H⋯O hydrogen bonds together with π–π interactions [centroid–centroid distances = 3.628 (3)–3.729 (3) Å] link neighboring molecules. |
format | Text |
id | pubmed-2961755 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29617552010-12-30 2-[(E)-(5-Amino-2,3-diphenylquinoxalin-6-yl)iminomethyl]-4-bromophenol Fun, Hoong-Kun Kia, Reza Raithby, Paul R. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(27)H(19)BrN(4)O, is a mono-anil Schiff base ligand. Three intramolecular O—H⋯N and N—H⋯N hydrogen bonds involving the hydroxy and amino groups generate S(6) and S(5) ring motifs, respectively. In the crystal structure, weak intermolecular N—H⋯O and C—H⋯O hydrogen bonds together with π–π interactions [centroid–centroid distances = 3.628 (3)–3.729 (3) Å] link neighboring molecules. International Union of Crystallography 2008-06-13 /pmc/articles/PMC2961755/ /pubmed/21202904 http://dx.doi.org/10.1107/S1600536808017716 Text en © Fun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Kia, Reza Raithby, Paul R. 2-[(E)-(5-Amino-2,3-diphenylquinoxalin-6-yl)iminomethyl]-4-bromophenol |
title | 2-[(E)-(5-Amino-2,3-diphenylquinoxalin-6-yl)iminomethyl]-4-bromophenol |
title_full | 2-[(E)-(5-Amino-2,3-diphenylquinoxalin-6-yl)iminomethyl]-4-bromophenol |
title_fullStr | 2-[(E)-(5-Amino-2,3-diphenylquinoxalin-6-yl)iminomethyl]-4-bromophenol |
title_full_unstemmed | 2-[(E)-(5-Amino-2,3-diphenylquinoxalin-6-yl)iminomethyl]-4-bromophenol |
title_short | 2-[(E)-(5-Amino-2,3-diphenylquinoxalin-6-yl)iminomethyl]-4-bromophenol |
title_sort | 2-[(e)-(5-amino-2,3-diphenylquinoxalin-6-yl)iminomethyl]-4-bromophenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961755/ https://www.ncbi.nlm.nih.gov/pubmed/21202904 http://dx.doi.org/10.1107/S1600536808017716 |
work_keys_str_mv | AT funhoongkun 2e5amino23diphenylquinoxalin6yliminomethyl4bromophenol AT kiareza 2e5amino23diphenylquinoxalin6yliminomethyl4bromophenol AT raithbypaulr 2e5amino23diphenylquinoxalin6yliminomethyl4bromophenol |