1,1′-Bis(diisobutyl­phosphino)cobalto­cenium hexa­fluorido­phosphate

In the title compound, [Co(C(13)H(22)P)(2)]PF(6), the Co(III) atom is sandwiched between two (diisobutyl­phosphino)cyclo­penta­dienenyl ligands. The two diisobutyl­phophine units are trans to each other with respect to the Co(III) metal center. The PF(6) (−) anion links the cobaltocenium cations via...

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Detalles Bibliográficos
Autores principales: Hou, Jian-Guo, Li, Ding-Biao, Qiu, Man-Zhen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961756/
https://www.ncbi.nlm.nih.gov/pubmed/21202782
http://dx.doi.org/10.1107/S1600536808017194
Descripción
Sumario:In the title compound, [Co(C(13)H(22)P)(2)]PF(6), the Co(III) atom is sandwiched between two (diisobutyl­phosphino)cyclo­penta­dienenyl ligands. The two diisobutyl­phophine units are trans to each other with respect to the Co(III) metal center. The PF(6) (−) anion links the cobaltocenium cations via weak C—H⋯F hydrogen bonds into a chain running along the b axis. The chains are further linked by C—H⋯F hydrogen bonds, forming a layer extending parallel to the (10[Image: see text]) plane.

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