1,1′-Bis(diisobutyl­phosphino)cobalto­cenium hexa­fluorido­phosphate

In the title compound, [Co(C(13)H(22)P)(2)]PF(6), the Co(III) atom is sandwiched between two (diisobutyl­phosphino)cyclo­penta­dienenyl ligands. The two diisobutyl­phophine units are trans to each other with respect to the Co(III) metal center. The PF(6) (−) anion links the cobaltocenium cations via...

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Detalles Bibliográficos
Autores principales: Hou, Jian-Guo, Li, Ding-Biao, Qiu, Man-Zhen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961756/
https://www.ncbi.nlm.nih.gov/pubmed/21202782
http://dx.doi.org/10.1107/S1600536808017194
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author Hou, Jian-Guo
Li, Ding-Biao
Qiu, Man-Zhen
author_facet Hou, Jian-Guo
Li, Ding-Biao
Qiu, Man-Zhen
author_sort Hou, Jian-Guo
collection PubMed
description In the title compound, [Co(C(13)H(22)P)(2)]PF(6), the Co(III) atom is sandwiched between two (diisobutyl­phosphino)cyclo­penta­dienenyl ligands. The two diisobutyl­phophine units are trans to each other with respect to the Co(III) metal center. The PF(6) (−) anion links the cobaltocenium cations via weak C—H⋯F hydrogen bonds into a chain running along the b axis. The chains are further linked by C—H⋯F hydrogen bonds, forming a layer extending parallel to the (10[Image: see text]) plane.
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spelling pubmed-29617562010-12-30 1,1′-Bis(diisobutyl­phosphino)cobalto­cenium hexa­fluorido­phosphate Hou, Jian-Guo Li, Ding-Biao Qiu, Man-Zhen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(13)H(22)P)(2)]PF(6), the Co(III) atom is sandwiched between two (diisobutyl­phosphino)cyclo­penta­dienenyl ligands. The two diisobutyl­phophine units are trans to each other with respect to the Co(III) metal center. The PF(6) (−) anion links the cobaltocenium cations via weak C—H⋯F hydrogen bonds into a chain running along the b axis. The chains are further linked by C—H⋯F hydrogen bonds, forming a layer extending parallel to the (10[Image: see text]) plane. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961756/ /pubmed/21202782 http://dx.doi.org/10.1107/S1600536808017194 Text en © Hou et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hou, Jian-Guo
Li, Ding-Biao
Qiu, Man-Zhen
1,1′-Bis(diisobutyl­phosphino)cobalto­cenium hexa­fluorido­phosphate
title 1,1′-Bis(diisobutyl­phosphino)cobalto­cenium hexa­fluorido­phosphate
title_full 1,1′-Bis(diisobutyl­phosphino)cobalto­cenium hexa­fluorido­phosphate
title_fullStr 1,1′-Bis(diisobutyl­phosphino)cobalto­cenium hexa­fluorido­phosphate
title_full_unstemmed 1,1′-Bis(diisobutyl­phosphino)cobalto­cenium hexa­fluorido­phosphate
title_short 1,1′-Bis(diisobutyl­phosphino)cobalto­cenium hexa­fluorido­phosphate
title_sort 1,1′-bis(diisobutyl­phosphino)cobalto­cenium hexa­fluorido­phosphate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961756/
https://www.ncbi.nlm.nih.gov/pubmed/21202782
http://dx.doi.org/10.1107/S1600536808017194
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AT lidingbiao 11bisdiisobutylphosphinocobaltoceniumhexafluoridophosphate
AT qiumanzhen 11bisdiisobutylphosphinocobaltoceniumhexafluoridophosphate

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