Dichlorido(methanol-κO)[2-(2-pyridyl­meth­oxy)-1,10-phenanthroline-κ(3) N,N′,N′′]manganese(II)

In the title mononuclear complex, [MnCl(2)(C(18)H(13)N(3)O)(CH(4)O)], the Mn(II) ion assumes a distorted octa­hedral geometry. There is a π–π stacking inter­action between the phenanthroline ligand and the pyridine ring of a neighboring complex [centroid-to-centroid distance 3.5518 (13) Å]. The crys...

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Detalles Bibliográficos
Autores principales: Li, Hong Liang, Chao, Hou
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961758/
https://www.ncbi.nlm.nih.gov/pubmed/21202809
http://dx.doi.org/10.1107/S1600536808018631
Descripción
Sumario:In the title mononuclear complex, [MnCl(2)(C(18)H(13)N(3)O)(CH(4)O)], the Mn(II) ion assumes a distorted octa­hedral geometry. There is a π–π stacking inter­action between the phenanthroline ligand and the pyridine ring of a neighboring complex [centroid-to-centroid distance 3.5518 (13) Å]. The crystal structure also contains weak inter­molecular O—H⋯Cl hydrogen bonds that link neighboring complex mol­ecules into a one-dimensional chain along the b axis.

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