Dichlorido(methanol-κO)[2-(2-pyridyl­meth­oxy)-1,10-phenanthroline-κ(3) N,N′,N′′]manganese(II)

In the title mononuclear complex, [MnCl(2)(C(18)H(13)N(3)O)(CH(4)O)], the Mn(II) ion assumes a distorted octa­hedral geometry. There is a π–π stacking inter­action between the phenanthroline ligand and the pyridine ring of a neighboring complex [centroid-to-centroid distance 3.5518 (13) Å]. The crys...

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Detalles Bibliográficos
Autores principales: Li, Hong Liang, Chao, Hou
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961758/
https://www.ncbi.nlm.nih.gov/pubmed/21202809
http://dx.doi.org/10.1107/S1600536808018631
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author Li, Hong Liang
Chao, Hou
author_facet Li, Hong Liang
Chao, Hou
author_sort Li, Hong Liang
collection PubMed
description In the title mononuclear complex, [MnCl(2)(C(18)H(13)N(3)O)(CH(4)O)], the Mn(II) ion assumes a distorted octa­hedral geometry. There is a π–π stacking inter­action between the phenanthroline ligand and the pyridine ring of a neighboring complex [centroid-to-centroid distance 3.5518 (13) Å]. The crystal structure also contains weak inter­molecular O—H⋯Cl hydrogen bonds that link neighboring complex mol­ecules into a one-dimensional chain along the b axis.
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spelling pubmed-29617582010-12-30 Dichlorido(methanol-κO)[2-(2-pyridyl­meth­oxy)-1,10-phenanthroline-κ(3) N,N′,N′′]manganese(II) Li, Hong Liang Chao, Hou Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [MnCl(2)(C(18)H(13)N(3)O)(CH(4)O)], the Mn(II) ion assumes a distorted octa­hedral geometry. There is a π–π stacking inter­action between the phenanthroline ligand and the pyridine ring of a neighboring complex [centroid-to-centroid distance 3.5518 (13) Å]. The crystal structure also contains weak inter­molecular O—H⋯Cl hydrogen bonds that link neighboring complex mol­ecules into a one-dimensional chain along the b axis. International Union of Crystallography 2008-06-25 /pmc/articles/PMC2961758/ /pubmed/21202809 http://dx.doi.org/10.1107/S1600536808018631 Text en © Li and Chao 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Hong Liang
Chao, Hou
Dichlorido(methanol-κO)[2-(2-pyridyl­meth­oxy)-1,10-phenanthroline-κ(3) N,N′,N′′]manganese(II)
title Dichlorido(methanol-κO)[2-(2-pyridyl­meth­oxy)-1,10-phenanthroline-κ(3) N,N′,N′′]manganese(II)
title_full Dichlorido(methanol-κO)[2-(2-pyridyl­meth­oxy)-1,10-phenanthroline-κ(3) N,N′,N′′]manganese(II)
title_fullStr Dichlorido(methanol-κO)[2-(2-pyridyl­meth­oxy)-1,10-phenanthroline-κ(3) N,N′,N′′]manganese(II)
title_full_unstemmed Dichlorido(methanol-κO)[2-(2-pyridyl­meth­oxy)-1,10-phenanthroline-κ(3) N,N′,N′′]manganese(II)
title_short Dichlorido(methanol-κO)[2-(2-pyridyl­meth­oxy)-1,10-phenanthroline-κ(3) N,N′,N′′]manganese(II)
title_sort dichlorido(methanol-κo)[2-(2-pyridyl­meth­oxy)-1,10-phenanthroline-κ(3) n,n′,n′′]manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961758/
https://www.ncbi.nlm.nih.gov/pubmed/21202809
http://dx.doi.org/10.1107/S1600536808018631
work_keys_str_mv AT lihongliang dichloridomethanolko22pyridylmethoxy110phenanthrolinek3nnnmanganeseii
AT chaohou dichloridomethanolko22pyridylmethoxy110phenanthrolinek3nnnmanganeseii

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