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N-(4-Chlorophenylsulfonyl)-2,2,2-trimethylacetamide
In the crystal structure of the title compound (N4CPSTMAA), C(11)H(14)ClNO(3)S, the conformations of the N—H and C=O bonds in the amide group are anti to each other, similar to those observed in N-phenylsulfonyl-2,2,2-trimethylacetamide (NPSTMAA) and 2,2,2-trimethyl-N-(4-methylphenylsulfonyl)ac...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961760/ https://www.ncbi.nlm.nih.gov/pubmed/21202911 http://dx.doi.org/10.1107/S1600536808017583 |
Sumario: | In the crystal structure of the title compound (N4CPSTMAA), C(11)H(14)ClNO(3)S, the conformations of the N—H and C=O bonds in the amide group are anti to each other, similar to those observed in N-phenylsulfonyl-2,2,2-trimethylacetamide (NPSTMAA) and 2,2,2-trimethyl-N-(4-methylphenylsulfonyl)acetamide (N4MPSTMAA). The bond parameters in N4CPSTMAA are similar to those in NPSTMAA, N4MPSTMAA, N-aryl-2,2,2-trimethylacetamides and 4-chlorobenzenesulfonamide. The –SNHCOC– unit including the amide group is essentially planar and makes a dihedral angle of 82.2 (1)° with the benzene ring, comparable to the values of 79.1 (1) and 71.2 (1)° in NPSTMAA and N4MPSTMAA, respectively. The molecules in N4CPSTMAA are linked into a chain by intermolecular N—H⋯O hydrogen bonds. |
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