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N-(4-Chloro­phenyl­sulfon­yl)-2,2,2-tri­methyl­acetamide

In the crystal structure of the title compound (N4CPSTMAA), C(11)H(14)ClNO(3)S, the conformations of the N—H and C=O bonds in the amide group are anti to each other, similar to those observed in N-phenyl­sulfonyl-2,2,2-trimethyl­acetamide (NPSTMAA) and 2,2,2-trimethyl-N-(4-methyl­phenyl­sulfon­yl)ac...

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Autores principales: Gowda, B. Thimme, Foro, Sabine, Sowmya, B. P., Nirmala, P. G., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961760/
https://www.ncbi.nlm.nih.gov/pubmed/21202911
http://dx.doi.org/10.1107/S1600536808017583
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author Gowda, B. Thimme
Foro, Sabine
Sowmya, B. P.
Nirmala, P. G.
Fuess, Hartmut
author_facet Gowda, B. Thimme
Foro, Sabine
Sowmya, B. P.
Nirmala, P. G.
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description In the crystal structure of the title compound (N4CPSTMAA), C(11)H(14)ClNO(3)S, the conformations of the N—H and C=O bonds in the amide group are anti to each other, similar to those observed in N-phenyl­sulfonyl-2,2,2-trimethyl­acetamide (NPSTMAA) and 2,2,2-trimethyl-N-(4-methyl­phenyl­sulfon­yl)acetamide (N4MPSTMAA). The bond parameters in N4CPSTMAA are similar to those in NPSTMAA, N4MPSTMAA, N-aryl-2,2,2-trimethyl­acetamides and 4-chloro­benzene­sulfonamide. The –SNHCOC– unit including the amide group is essentially planar and makes a dihedral angle of 82.2 (1)° with the benzene ring, comparable to the values of 79.1 (1) and 71.2 (1)° in NPSTMAA and N4MPSTMAA, respectively. The mol­ecules in N4CPSTMAA are linked into a chain by inter­molecular N—H⋯O hydrogen bonds.
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spelling pubmed-29617602010-12-30 N-(4-Chloro­phenyl­sulfon­yl)-2,2,2-tri­methyl­acetamide Gowda, B. Thimme Foro, Sabine Sowmya, B. P. Nirmala, P. G. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound (N4CPSTMAA), C(11)H(14)ClNO(3)S, the conformations of the N—H and C=O bonds in the amide group are anti to each other, similar to those observed in N-phenyl­sulfonyl-2,2,2-trimethyl­acetamide (NPSTMAA) and 2,2,2-trimethyl-N-(4-methyl­phenyl­sulfon­yl)acetamide (N4MPSTMAA). The bond parameters in N4CPSTMAA are similar to those in NPSTMAA, N4MPSTMAA, N-aryl-2,2,2-trimethyl­acetamides and 4-chloro­benzene­sulfonamide. The –SNHCOC– unit including the amide group is essentially planar and makes a dihedral angle of 82.2 (1)° with the benzene ring, comparable to the values of 79.1 (1) and 71.2 (1)° in NPSTMAA and N4MPSTMAA, respectively. The mol­ecules in N4CPSTMAA are linked into a chain by inter­molecular N—H⋯O hydrogen bonds. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961760/ /pubmed/21202911 http://dx.doi.org/10.1107/S1600536808017583 Text en © Gowda et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Foro, Sabine
Sowmya, B. P.
Nirmala, P. G.
Fuess, Hartmut
N-(4-Chloro­phenyl­sulfon­yl)-2,2,2-tri­methyl­acetamide
title N-(4-Chloro­phenyl­sulfon­yl)-2,2,2-tri­methyl­acetamide
title_full N-(4-Chloro­phenyl­sulfon­yl)-2,2,2-tri­methyl­acetamide
title_fullStr N-(4-Chloro­phenyl­sulfon­yl)-2,2,2-tri­methyl­acetamide
title_full_unstemmed N-(4-Chloro­phenyl­sulfon­yl)-2,2,2-tri­methyl­acetamide
title_short N-(4-Chloro­phenyl­sulfon­yl)-2,2,2-tri­methyl­acetamide
title_sort n-(4-chloro­phenyl­sulfon­yl)-2,2,2-tri­methyl­acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961760/
https://www.ncbi.nlm.nih.gov/pubmed/21202911
http://dx.doi.org/10.1107/S1600536808017583
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