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N-(4-Chlorophenylsulfonyl)-2,2,2-trimethylacetamide
In the crystal structure of the title compound (N4CPSTMAA), C(11)H(14)ClNO(3)S, the conformations of the N—H and C=O bonds in the amide group are anti to each other, similar to those observed in N-phenylsulfonyl-2,2,2-trimethylacetamide (NPSTMAA) and 2,2,2-trimethyl-N-(4-methylphenylsulfonyl)ac...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961760/ https://www.ncbi.nlm.nih.gov/pubmed/21202911 http://dx.doi.org/10.1107/S1600536808017583 |
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author | Gowda, B. Thimme Foro, Sabine Sowmya, B. P. Nirmala, P. G. Fuess, Hartmut |
author_facet | Gowda, B. Thimme Foro, Sabine Sowmya, B. P. Nirmala, P. G. Fuess, Hartmut |
author_sort | Gowda, B. Thimme |
collection | PubMed |
description | In the crystal structure of the title compound (N4CPSTMAA), C(11)H(14)ClNO(3)S, the conformations of the N—H and C=O bonds in the amide group are anti to each other, similar to those observed in N-phenylsulfonyl-2,2,2-trimethylacetamide (NPSTMAA) and 2,2,2-trimethyl-N-(4-methylphenylsulfonyl)acetamide (N4MPSTMAA). The bond parameters in N4CPSTMAA are similar to those in NPSTMAA, N4MPSTMAA, N-aryl-2,2,2-trimethylacetamides and 4-chlorobenzenesulfonamide. The –SNHCOC– unit including the amide group is essentially planar and makes a dihedral angle of 82.2 (1)° with the benzene ring, comparable to the values of 79.1 (1) and 71.2 (1)° in NPSTMAA and N4MPSTMAA, respectively. The molecules in N4CPSTMAA are linked into a chain by intermolecular N—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2961760 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29617602010-12-30 N-(4-Chlorophenylsulfonyl)-2,2,2-trimethylacetamide Gowda, B. Thimme Foro, Sabine Sowmya, B. P. Nirmala, P. G. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound (N4CPSTMAA), C(11)H(14)ClNO(3)S, the conformations of the N—H and C=O bonds in the amide group are anti to each other, similar to those observed in N-phenylsulfonyl-2,2,2-trimethylacetamide (NPSTMAA) and 2,2,2-trimethyl-N-(4-methylphenylsulfonyl)acetamide (N4MPSTMAA). The bond parameters in N4CPSTMAA are similar to those in NPSTMAA, N4MPSTMAA, N-aryl-2,2,2-trimethylacetamides and 4-chlorobenzenesulfonamide. The –SNHCOC– unit including the amide group is essentially planar and makes a dihedral angle of 82.2 (1)° with the benzene ring, comparable to the values of 79.1 (1) and 71.2 (1)° in NPSTMAA and N4MPSTMAA, respectively. The molecules in N4CPSTMAA are linked into a chain by intermolecular N—H⋯O hydrogen bonds. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961760/ /pubmed/21202911 http://dx.doi.org/10.1107/S1600536808017583 Text en © Gowda et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Gowda, B. Thimme Foro, Sabine Sowmya, B. P. Nirmala, P. G. Fuess, Hartmut N-(4-Chlorophenylsulfonyl)-2,2,2-trimethylacetamide |
title |
N-(4-Chlorophenylsulfonyl)-2,2,2-trimethylacetamide |
title_full |
N-(4-Chlorophenylsulfonyl)-2,2,2-trimethylacetamide |
title_fullStr |
N-(4-Chlorophenylsulfonyl)-2,2,2-trimethylacetamide |
title_full_unstemmed |
N-(4-Chlorophenylsulfonyl)-2,2,2-trimethylacetamide |
title_short |
N-(4-Chlorophenylsulfonyl)-2,2,2-trimethylacetamide |
title_sort | n-(4-chlorophenylsulfonyl)-2,2,2-trimethylacetamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961760/ https://www.ncbi.nlm.nih.gov/pubmed/21202911 http://dx.doi.org/10.1107/S1600536808017583 |
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