2,2′-(p-Phenyl­ene)bis­(1,4,5,6-tetra­hydro­pyrimidinium) bis­[dicyanidoargentate(I)]

The asymmetric unit of the title compound, (C(14)H(20)N(4))[Ag(CN)(2)](2), contains one-half of a centrosymmetric 2,2′-(p-phenyl­ene)bis­(1,4,5,6-tetra­hydro­pyrimidinium) (H(2)btb) cation and one [Ag(CN)(2)](−) anion. In the anions, the Ag(I) atoms adopt near linear coordination modes with the two...

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Detalles Bibliográficos
Autores principales: Jiang, Zhi-Yu, Dong, Hua-Ze, Zhang, Gong, Cheng, Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961762/
https://www.ncbi.nlm.nih.gov/pubmed/21202735
http://dx.doi.org/10.1107/S1600536808015791
Descripción
Sumario:The asymmetric unit of the title compound, (C(14)H(20)N(4))[Ag(CN)(2)](2), contains one-half of a centrosymmetric 2,2′-(p-phenyl­ene)bis­(1,4,5,6-tetra­hydro­pyrimidinium) (H(2)btb) cation and one [Ag(CN)(2)](−) anion. In the anions, the Ag(I) atoms adopt near linear coordination modes with the two attached cyanide groups [C—Ag—C = 173.3 (2)°]. In the crystal structure, each H(2)btb cation links four [Ag(CN)(2)](−) anions via N—H⋯N hydrogen bonds into a one-dimensional ribbon.

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