catena-Poly[[[diaqua­nickel(II)]-di-μ-glycine] dichloride]

In the polymeric title complex, {[Ni(C(2)H(5)NO(2))(2)(H(2)O)(2)]Cl(2)}(n), the Ni(II) atom lies on an inversion center and is in a distorted octa­hedral NiO(6) configuration, with four carboxyl­ate O atoms from four zwitterionic glycine mol­ecules forming the equatorial plane and two water O atoms...

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Detalles Bibliográficos
Autores principales: Ch’ng, Cynn Dee, Teoh, Siang Guan, Chantrapromma, Suchada, Fun, Hoong-Kun, Goh, Siu Mun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961767/
https://www.ncbi.nlm.nih.gov/pubmed/21202740
http://dx.doi.org/10.1107/S1600536808015894
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author Ch’ng, Cynn Dee
Teoh, Siang Guan
Chantrapromma, Suchada
Fun, Hoong-Kun
Goh, Siu Mun
author_facet Ch’ng, Cynn Dee
Teoh, Siang Guan
Chantrapromma, Suchada
Fun, Hoong-Kun
Goh, Siu Mun
author_sort Ch’ng, Cynn Dee
collection PubMed
description In the polymeric title complex, {[Ni(C(2)H(5)NO(2))(2)(H(2)O)(2)]Cl(2)}(n), the Ni(II) atom lies on an inversion center and is in a distorted octa­hedral NiO(6) configuration, with four carboxyl­ate O atoms from four zwitterionic glycine mol­ecules forming the equatorial plane and two water O atoms occupying the axial positions. The Cl(−) counterions lie in the inter­stices. The Ni(II) complexes are linked into polymeric sheets parallel to the bc plane. These sheets are then further connected into a three-dimensional network by O—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen bonds, together with weak C—H⋯O inter­actions.
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spelling pubmed-29617672010-12-30 catena-Poly[[[diaqua­nickel(II)]-di-μ-glycine] dichloride] Ch’ng, Cynn Dee Teoh, Siang Guan Chantrapromma, Suchada Fun, Hoong-Kun Goh, Siu Mun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the polymeric title complex, {[Ni(C(2)H(5)NO(2))(2)(H(2)O)(2)]Cl(2)}(n), the Ni(II) atom lies on an inversion center and is in a distorted octa­hedral NiO(6) configuration, with four carboxyl­ate O atoms from four zwitterionic glycine mol­ecules forming the equatorial plane and two water O atoms occupying the axial positions. The Cl(−) counterions lie in the inter­stices. The Ni(II) complexes are linked into polymeric sheets parallel to the bc plane. These sheets are then further connected into a three-dimensional network by O—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen bonds, together with weak C—H⋯O inter­actions. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961767/ /pubmed/21202740 http://dx.doi.org/10.1107/S1600536808015894 Text en © Ch'ng et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ch’ng, Cynn Dee
Teoh, Siang Guan
Chantrapromma, Suchada
Fun, Hoong-Kun
Goh, Siu Mun
catena-Poly[[[diaqua­nickel(II)]-di-μ-glycine] dichloride]
title catena-Poly[[[diaqua­nickel(II)]-di-μ-glycine] dichloride]
title_full catena-Poly[[[diaqua­nickel(II)]-di-μ-glycine] dichloride]
title_fullStr catena-Poly[[[diaqua­nickel(II)]-di-μ-glycine] dichloride]
title_full_unstemmed catena-Poly[[[diaqua­nickel(II)]-di-μ-glycine] dichloride]
title_short catena-Poly[[[diaqua­nickel(II)]-di-μ-glycine] dichloride]
title_sort catena-poly[[[diaqua­nickel(ii)]-di-μ-glycine] dichloride]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961767/
https://www.ncbi.nlm.nih.gov/pubmed/21202740
http://dx.doi.org/10.1107/S1600536808015894
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