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Tetrakis(4-aminopyridine-κN (1))dichloridocopper(II) monohydrate
The asymmetric unit of the title compound, [CuCl(2)(C(5)H(6)N(2))(4)]·H(2)O, contains two crystallographically independent complex molecules and two water molecules. The Cu(II) ion in each molecule is six-coordinated in an elongated octahedral geometry, with the equatorial plane defined by four...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961768/ https://www.ncbi.nlm.nih.gov/pubmed/21202731 http://dx.doi.org/10.1107/S1600536808015778 |
Sumario: | The asymmetric unit of the title compound, [CuCl(2)(C(5)H(6)N(2))(4)]·H(2)O, contains two crystallographically independent complex molecules and two water molecules. The Cu(II) ion in each molecule is six-coordinated in an elongated octahedral geometry, with the equatorial plane defined by four pyridine N atoms of four aminopyridine ligands and the axial positions occupied by two Cl atoms. In the crystal structure, molecules are linked into a three-dimensional framework by C—H⋯Cl, O—H⋯Cl, N—H⋯O, N—H⋯Cl and N—H⋯N hydrogen bonds and C/N—H⋯π interactions involving the pyridine rings. |
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