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Tetra­kis(4-amino­pyridine-κN (1))dichlorido­copper(II) monohydrate

The asymmetric unit of the title compound, [CuCl(2)(C(5)H(6)N(2))(4)]·H(2)O, contains two crystallographically independent complex mol­ecules and two water mol­ecules. The Cu(II) ion in each mol­ecule is six-coordinated in an elongated octa­hedral geometry, with the equatorial plane defined by four...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Sinthya, A., Jebas, Samuel Robinson, Devadasan, Suganthi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961768/
https://www.ncbi.nlm.nih.gov/pubmed/21202731
http://dx.doi.org/10.1107/S1600536808015778
Descripción
Sumario:The asymmetric unit of the title compound, [CuCl(2)(C(5)H(6)N(2))(4)]·H(2)O, contains two crystallographically independent complex mol­ecules and two water mol­ecules. The Cu(II) ion in each mol­ecule is six-coordinated in an elongated octa­hedral geometry, with the equatorial plane defined by four pyridine N atoms of four amino­pyridine ligands and the axial positions occupied by two Cl atoms. In the crystal structure, mol­ecules are linked into a three-dimensional framework by C—H⋯Cl, O—H⋯Cl, N—H⋯O, N—H⋯Cl and N—H⋯N hydrogen bonds and C/N—H⋯π inter­actions involving the pyridine rings.