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Tetra­kis(4-amino­pyridine-κN (1))dichlorido­copper(II) monohydrate

The asymmetric unit of the title compound, [CuCl(2)(C(5)H(6)N(2))(4)]·H(2)O, contains two crystallographically independent complex mol­ecules and two water mol­ecules. The Cu(II) ion in each mol­ecule is six-coordinated in an elongated octa­hedral geometry, with the equatorial plane defined by four...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Sinthya, A., Jebas, Samuel Robinson, Devadasan, Suganthi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961768/
https://www.ncbi.nlm.nih.gov/pubmed/21202731
http://dx.doi.org/10.1107/S1600536808015778
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author Fun, Hoong-Kun
Sinthya, A.
Jebas, Samuel Robinson
Devadasan, Suganthi
author_facet Fun, Hoong-Kun
Sinthya, A.
Jebas, Samuel Robinson
Devadasan, Suganthi
author_sort Fun, Hoong-Kun
collection PubMed
description The asymmetric unit of the title compound, [CuCl(2)(C(5)H(6)N(2))(4)]·H(2)O, contains two crystallographically independent complex mol­ecules and two water mol­ecules. The Cu(II) ion in each mol­ecule is six-coordinated in an elongated octa­hedral geometry, with the equatorial plane defined by four pyridine N atoms of four amino­pyridine ligands and the axial positions occupied by two Cl atoms. In the crystal structure, mol­ecules are linked into a three-dimensional framework by C—H⋯Cl, O—H⋯Cl, N—H⋯O, N—H⋯Cl and N—H⋯N hydrogen bonds and C/N—H⋯π inter­actions involving the pyridine rings.
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spelling pubmed-29617682010-12-30 Tetra­kis(4-amino­pyridine-κN (1))dichlorido­copper(II) monohydrate Fun, Hoong-Kun Sinthya, A. Jebas, Samuel Robinson Devadasan, Suganthi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [CuCl(2)(C(5)H(6)N(2))(4)]·H(2)O, contains two crystallographically independent complex mol­ecules and two water mol­ecules. The Cu(II) ion in each mol­ecule is six-coordinated in an elongated octa­hedral geometry, with the equatorial plane defined by four pyridine N atoms of four amino­pyridine ligands and the axial positions occupied by two Cl atoms. In the crystal structure, mol­ecules are linked into a three-dimensional framework by C—H⋯Cl, O—H⋯Cl, N—H⋯O, N—H⋯Cl and N—H⋯N hydrogen bonds and C/N—H⋯π inter­actions involving the pyridine rings. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961768/ /pubmed/21202731 http://dx.doi.org/10.1107/S1600536808015778 Text en © Fun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fun, Hoong-Kun
Sinthya, A.
Jebas, Samuel Robinson
Devadasan, Suganthi
Tetra­kis(4-amino­pyridine-κN (1))dichlorido­copper(II) monohydrate
title Tetra­kis(4-amino­pyridine-κN (1))dichlorido­copper(II) monohydrate
title_full Tetra­kis(4-amino­pyridine-κN (1))dichlorido­copper(II) monohydrate
title_fullStr Tetra­kis(4-amino­pyridine-κN (1))dichlorido­copper(II) monohydrate
title_full_unstemmed Tetra­kis(4-amino­pyridine-κN (1))dichlorido­copper(II) monohydrate
title_short Tetra­kis(4-amino­pyridine-κN (1))dichlorido­copper(II) monohydrate
title_sort tetra­kis(4-amino­pyridine-κn (1))dichlorido­copper(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961768/
https://www.ncbi.nlm.nih.gov/pubmed/21202731
http://dx.doi.org/10.1107/S1600536808015778
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