Bis(pentane-2,4-dionato)bis­[2-(4-pyrid­yl)-4,4,5,5-tetra­methyl­imidazoline-1-oxyl 3-oxide]nickel(II)

In the title compound, [Ni(C(5)H(7)O(2))(2)(C(12)H(16)N(3)O(2))], the Ni(II) cation is hexa­coordinated by four O and two N atoms, showing a slightly distorted octa­hedral geometry. The Ni(II) cation lies on an inversion centre, as a consequence of which the asymmetric unit comprises one half-mol­ec...

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Detalles Bibliográficos
Autores principales: Hao, Lujiang, Mu, Chunhua, Kong, Binbin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961770/
https://www.ncbi.nlm.nih.gov/pubmed/21202806
http://dx.doi.org/10.1107/S1600536808018552
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author Hao, Lujiang
Mu, Chunhua
Kong, Binbin
author_facet Hao, Lujiang
Mu, Chunhua
Kong, Binbin
author_sort Hao, Lujiang
collection PubMed
description In the title compound, [Ni(C(5)H(7)O(2))(2)(C(12)H(16)N(3)O(2))], the Ni(II) cation is hexa­coordinated by four O and two N atoms, showing a slightly distorted octa­hedral geometry. The Ni(II) cation lies on an inversion centre, as a consequence of which the asymmetric unit comprises one half-mol­ecule. The four O atoms belonging to two pentane-2,4-dionate ligands lie in the equatorial plane and two pyridyl N atoms occupy the axial coordination sites.
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spelling pubmed-29617702010-12-30 Bis(pentane-2,4-dionato)bis­[2-(4-pyrid­yl)-4,4,5,5-tetra­methyl­imidazoline-1-oxyl 3-oxide]nickel(II) Hao, Lujiang Mu, Chunhua Kong, Binbin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(5)H(7)O(2))(2)(C(12)H(16)N(3)O(2))], the Ni(II) cation is hexa­coordinated by four O and two N atoms, showing a slightly distorted octa­hedral geometry. The Ni(II) cation lies on an inversion centre, as a consequence of which the asymmetric unit comprises one half-mol­ecule. The four O atoms belonging to two pentane-2,4-dionate ligands lie in the equatorial plane and two pyridyl N atoms occupy the axial coordination sites. International Union of Crystallography 2008-06-25 /pmc/articles/PMC2961770/ /pubmed/21202806 http://dx.doi.org/10.1107/S1600536808018552 Text en © Hao et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hao, Lujiang
Mu, Chunhua
Kong, Binbin
Bis(pentane-2,4-dionato)bis­[2-(4-pyrid­yl)-4,4,5,5-tetra­methyl­imidazoline-1-oxyl 3-oxide]nickel(II)
title Bis(pentane-2,4-dionato)bis­[2-(4-pyrid­yl)-4,4,5,5-tetra­methyl­imidazoline-1-oxyl 3-oxide]nickel(II)
title_full Bis(pentane-2,4-dionato)bis­[2-(4-pyrid­yl)-4,4,5,5-tetra­methyl­imidazoline-1-oxyl 3-oxide]nickel(II)
title_fullStr Bis(pentane-2,4-dionato)bis­[2-(4-pyrid­yl)-4,4,5,5-tetra­methyl­imidazoline-1-oxyl 3-oxide]nickel(II)
title_full_unstemmed Bis(pentane-2,4-dionato)bis­[2-(4-pyrid­yl)-4,4,5,5-tetra­methyl­imidazoline-1-oxyl 3-oxide]nickel(II)
title_short Bis(pentane-2,4-dionato)bis­[2-(4-pyrid­yl)-4,4,5,5-tetra­methyl­imidazoline-1-oxyl 3-oxide]nickel(II)
title_sort bis(pentane-2,4-dionato)bis­[2-(4-pyrid­yl)-4,4,5,5-tetra­methyl­imidazoline-1-oxyl 3-oxide]nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961770/
https://www.ncbi.nlm.nih.gov/pubmed/21202806
http://dx.doi.org/10.1107/S1600536808018552
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AT muchunhua bispentane24dionatobis24pyridyl4455tetramethylimidazoline1oxyl3oxidenickelii
AT kongbinbin bispentane24dionatobis24pyridyl4455tetramethylimidazoline1oxyl3oxidenickelii

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