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Poly[[diaqua-μ(4)-pyrazine-2,3-dicarboxylato-κ(6) N,O (2):O (2′):O (3),O (3′):O (3)-strontium(II)] monohydrate]
In the title compound, {[Sr(C(6)H(2)N(2)O(4))(H(2)O)(2)]·H(2)O}(n), the Sr(II) ions are bridged by the pyrazine-2,3-dicarboxylate ligands with the formation of two-dimensional polymeric layers parallel to the ac plane. Each Sr(II) ion is eight-coordinated by one N and five O atoms from the four lig...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961772/ https://www.ncbi.nlm.nih.gov/pubmed/21202756 http://dx.doi.org/10.1107/S1600536808015316 |
Sumario: | In the title compound, {[Sr(C(6)H(2)N(2)O(4))(H(2)O)(2)]·H(2)O}(n), the Sr(II) ions are bridged by the pyrazine-2,3-dicarboxylate ligands with the formation of two-dimensional polymeric layers parallel to the ac plane. Each Sr(II) ion is eight-coordinated by one N and five O atoms from the four ligands and two water molecules. The coordination polyhedron is derived from a pentagonal bipyramid with an O atom at the apex on one side of the equatorial plane and two O atoms sharing the apical site on the other side. The coordinated and uncoordinated water molecules are involved in O—H⋯O and O—H⋯N hydrogen bonds, which consolidate the crystal structure. |
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