Cargando…

Poly[[diaqua-μ(4)-pyrazine-2,3-dicarboxyl­ato-κ(6) N,O (2):O (2′):O (3),O (3′):O (3)-strontium(II)] monohydrate]

In the title compound, {[Sr(C(6)H(2)N(2)O(4))(H(2)O)(2)]·H(2)O}(n), the Sr(II) ions are bridged by the pyrazine-2,3-dicarboxyl­ate ligands with the formation of two-dimensional polymeric layers parallel to the ac plane. Each Sr(II) ion is eight-coordinated by one N and five O atoms from the four lig...

Descripción completa

Detalles Bibliográficos
Autores principales: Abedi, Anita, Mousavi Mirkolaei, Maryam, Amani, Vahid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961772/
https://www.ncbi.nlm.nih.gov/pubmed/21202756
http://dx.doi.org/10.1107/S1600536808015316
_version_ 1782189062366429184
author Abedi, Anita
Mousavi Mirkolaei, Maryam
Amani, Vahid
author_facet Abedi, Anita
Mousavi Mirkolaei, Maryam
Amani, Vahid
author_sort Abedi, Anita
collection PubMed
description In the title compound, {[Sr(C(6)H(2)N(2)O(4))(H(2)O)(2)]·H(2)O}(n), the Sr(II) ions are bridged by the pyrazine-2,3-dicarboxyl­ate ligands with the formation of two-dimensional polymeric layers parallel to the ac plane. Each Sr(II) ion is eight-coordinated by one N and five O atoms from the four ligands and two water mol­ecules. The coordination polyhedron is derived from a penta­gonal bipyramid with an O atom at the apex on one side of the equatorial plane and two O atoms sharing the apical site on the other side. The coordinated and uncoordinated water mol­ecules are involved in O—H⋯O and O—H⋯N hydrogen bonds, which consolidate the crystal structure.
format Text
id pubmed-2961772
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29617722010-12-30 Poly[[diaqua-μ(4)-pyrazine-2,3-dicarboxyl­ato-κ(6) N,O (2):O (2′):O (3),O (3′):O (3)-strontium(II)] monohydrate] Abedi, Anita Mousavi Mirkolaei, Maryam Amani, Vahid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Sr(C(6)H(2)N(2)O(4))(H(2)O)(2)]·H(2)O}(n), the Sr(II) ions are bridged by the pyrazine-2,3-dicarboxyl­ate ligands with the formation of two-dimensional polymeric layers parallel to the ac plane. Each Sr(II) ion is eight-coordinated by one N and five O atoms from the four ligands and two water mol­ecules. The coordination polyhedron is derived from a penta­gonal bipyramid with an O atom at the apex on one side of the equatorial plane and two O atoms sharing the apical site on the other side. The coordinated and uncoordinated water mol­ecules are involved in O—H⋯O and O—H⋯N hydrogen bonds, which consolidate the crystal structure. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961772/ /pubmed/21202756 http://dx.doi.org/10.1107/S1600536808015316 Text en © Abedi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Abedi, Anita
Mousavi Mirkolaei, Maryam
Amani, Vahid
Poly[[diaqua-μ(4)-pyrazine-2,3-dicarboxyl­ato-κ(6) N,O (2):O (2′):O (3),O (3′):O (3)-strontium(II)] monohydrate]
title Poly[[diaqua-μ(4)-pyrazine-2,3-dicarboxyl­ato-κ(6) N,O (2):O (2′):O (3),O (3′):O (3)-strontium(II)] monohydrate]
title_full Poly[[diaqua-μ(4)-pyrazine-2,3-dicarboxyl­ato-κ(6) N,O (2):O (2′):O (3),O (3′):O (3)-strontium(II)] monohydrate]
title_fullStr Poly[[diaqua-μ(4)-pyrazine-2,3-dicarboxyl­ato-κ(6) N,O (2):O (2′):O (3),O (3′):O (3)-strontium(II)] monohydrate]
title_full_unstemmed Poly[[diaqua-μ(4)-pyrazine-2,3-dicarboxyl­ato-κ(6) N,O (2):O (2′):O (3),O (3′):O (3)-strontium(II)] monohydrate]
title_short Poly[[diaqua-μ(4)-pyrazine-2,3-dicarboxyl­ato-κ(6) N,O (2):O (2′):O (3),O (3′):O (3)-strontium(II)] monohydrate]
title_sort poly[[diaqua-μ(4)-pyrazine-2,3-dicarboxyl­ato-κ(6) n,o (2):o (2′):o (3),o (3′):o (3)-strontium(ii)] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961772/
https://www.ncbi.nlm.nih.gov/pubmed/21202756
http://dx.doi.org/10.1107/S1600536808015316
work_keys_str_mv AT abedianita polydiaquam4pyrazine23dicarboxylatok6no2o2o3o3o3strontiumiimonohydrate
AT mousavimirkolaeimaryam polydiaquam4pyrazine23dicarboxylatok6no2o2o3o3o3strontiumiimonohydrate
AT amanivahid polydiaquam4pyrazine23dicarboxylatok6no2o2o3o3o3strontiumiimonohydrate