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Poly[[diaqua-μ(4)-pyrazine-2,3-dicarboxylato-κ(6) N,O (2):O (2′):O (3),O (3′):O (3)-strontium(II)] monohydrate]
In the title compound, {[Sr(C(6)H(2)N(2)O(4))(H(2)O)(2)]·H(2)O}(n), the Sr(II) ions are bridged by the pyrazine-2,3-dicarboxylate ligands with the formation of two-dimensional polymeric layers parallel to the ac plane. Each Sr(II) ion is eight-coordinated by one N and five O atoms from the four lig...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961772/ https://www.ncbi.nlm.nih.gov/pubmed/21202756 http://dx.doi.org/10.1107/S1600536808015316 |
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author | Abedi, Anita Mousavi Mirkolaei, Maryam Amani, Vahid |
author_facet | Abedi, Anita Mousavi Mirkolaei, Maryam Amani, Vahid |
author_sort | Abedi, Anita |
collection | PubMed |
description | In the title compound, {[Sr(C(6)H(2)N(2)O(4))(H(2)O)(2)]·H(2)O}(n), the Sr(II) ions are bridged by the pyrazine-2,3-dicarboxylate ligands with the formation of two-dimensional polymeric layers parallel to the ac plane. Each Sr(II) ion is eight-coordinated by one N and five O atoms from the four ligands and two water molecules. The coordination polyhedron is derived from a pentagonal bipyramid with an O atom at the apex on one side of the equatorial plane and two O atoms sharing the apical site on the other side. The coordinated and uncoordinated water molecules are involved in O—H⋯O and O—H⋯N hydrogen bonds, which consolidate the crystal structure. |
format | Text |
id | pubmed-2961772 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29617722010-12-30 Poly[[diaqua-μ(4)-pyrazine-2,3-dicarboxylato-κ(6) N,O (2):O (2′):O (3),O (3′):O (3)-strontium(II)] monohydrate] Abedi, Anita Mousavi Mirkolaei, Maryam Amani, Vahid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Sr(C(6)H(2)N(2)O(4))(H(2)O)(2)]·H(2)O}(n), the Sr(II) ions are bridged by the pyrazine-2,3-dicarboxylate ligands with the formation of two-dimensional polymeric layers parallel to the ac plane. Each Sr(II) ion is eight-coordinated by one N and five O atoms from the four ligands and two water molecules. The coordination polyhedron is derived from a pentagonal bipyramid with an O atom at the apex on one side of the equatorial plane and two O atoms sharing the apical site on the other side. The coordinated and uncoordinated water molecules are involved in O—H⋯O and O—H⋯N hydrogen bonds, which consolidate the crystal structure. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961772/ /pubmed/21202756 http://dx.doi.org/10.1107/S1600536808015316 Text en © Abedi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Abedi, Anita Mousavi Mirkolaei, Maryam Amani, Vahid Poly[[diaqua-μ(4)-pyrazine-2,3-dicarboxylato-κ(6) N,O (2):O (2′):O (3),O (3′):O (3)-strontium(II)] monohydrate] |
title | Poly[[diaqua-μ(4)-pyrazine-2,3-dicarboxylato-κ(6)
N,O
(2):O
(2′):O
(3),O
(3′):O
(3)-strontium(II)] monohydrate] |
title_full | Poly[[diaqua-μ(4)-pyrazine-2,3-dicarboxylato-κ(6)
N,O
(2):O
(2′):O
(3),O
(3′):O
(3)-strontium(II)] monohydrate] |
title_fullStr | Poly[[diaqua-μ(4)-pyrazine-2,3-dicarboxylato-κ(6)
N,O
(2):O
(2′):O
(3),O
(3′):O
(3)-strontium(II)] monohydrate] |
title_full_unstemmed | Poly[[diaqua-μ(4)-pyrazine-2,3-dicarboxylato-κ(6)
N,O
(2):O
(2′):O
(3),O
(3′):O
(3)-strontium(II)] monohydrate] |
title_short | Poly[[diaqua-μ(4)-pyrazine-2,3-dicarboxylato-κ(6)
N,O
(2):O
(2′):O
(3),O
(3′):O
(3)-strontium(II)] monohydrate] |
title_sort | poly[[diaqua-μ(4)-pyrazine-2,3-dicarboxylato-κ(6)
n,o
(2):o
(2′):o
(3),o
(3′):o
(3)-strontium(ii)] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961772/ https://www.ncbi.nlm.nih.gov/pubmed/21202756 http://dx.doi.org/10.1107/S1600536808015316 |
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