12-Nitro­methyl-14-deoxy­andro­graph­olide

In the mol­ecule of the title compound {systematic name: 3-[2-(6-hydr­oxy-5-hydroxy­methyl-5,8a-dimethyl-2-methyl­ene­per­hydro-1-napth­yl)-1-(nitro­meth­yl)eth­yl]-2(4H)-furan­one}, C(21)H(31)NO(6), the cyclo­hexane rings have chair conformations. Intra­molecular O—H⋯O hydrogen bonding results in t...

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Detalles Bibliográficos
Autores principales: Quan, Ji-Cai, Chen, Jing, Xu, Hao, Hu, Chen-Hui, Wang, Jin-Tang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961773/
https://www.ncbi.nlm.nih.gov/pubmed/21202965
http://dx.doi.org/10.1107/S1600536808018746
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author Quan, Ji-Cai
Chen, Jing
Xu, Hao
Hu, Chen-Hui
Wang, Jin-Tang
author_facet Quan, Ji-Cai
Chen, Jing
Xu, Hao
Hu, Chen-Hui
Wang, Jin-Tang
author_sort Quan, Ji-Cai
collection PubMed
description In the mol­ecule of the title compound {systematic name: 3-[2-(6-hydr­oxy-5-hydroxy­methyl-5,8a-dimethyl-2-methyl­ene­per­hydro-1-napth­yl)-1-(nitro­meth­yl)eth­yl]-2(4H)-furan­one}, C(21)H(31)NO(6), the cyclo­hexane rings have chair conformations. Intra­molecular O—H⋯O hydrogen bonding results in the formation of a six-membered non-planar ring with a twist conformation. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules into infinite chains along the c axis.
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spelling pubmed-29617732010-12-30 12-Nitro­methyl-14-deoxy­andro­graph­olide Quan, Ji-Cai Chen, Jing Xu, Hao Hu, Chen-Hui Wang, Jin-Tang Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound {systematic name: 3-[2-(6-hydr­oxy-5-hydroxy­methyl-5,8a-dimethyl-2-methyl­ene­per­hydro-1-napth­yl)-1-(nitro­meth­yl)eth­yl]-2(4H)-furan­one}, C(21)H(31)NO(6), the cyclo­hexane rings have chair conformations. Intra­molecular O—H⋯O hydrogen bonding results in the formation of a six-membered non-planar ring with a twist conformation. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules into infinite chains along the c axis. International Union of Crystallography 2008-06-28 /pmc/articles/PMC2961773/ /pubmed/21202965 http://dx.doi.org/10.1107/S1600536808018746 Text en © Quan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Quan, Ji-Cai
Chen, Jing
Xu, Hao
Hu, Chen-Hui
Wang, Jin-Tang
12-Nitro­methyl-14-deoxy­andro­graph­olide
title 12-Nitro­methyl-14-deoxy­andro­graph­olide
title_full 12-Nitro­methyl-14-deoxy­andro­graph­olide
title_fullStr 12-Nitro­methyl-14-deoxy­andro­graph­olide
title_full_unstemmed 12-Nitro­methyl-14-deoxy­andro­graph­olide
title_short 12-Nitro­methyl-14-deoxy­andro­graph­olide
title_sort 12-nitro­methyl-14-deoxy­andro­graph­olide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961773/
https://www.ncbi.nlm.nih.gov/pubmed/21202965
http://dx.doi.org/10.1107/S1600536808018746
work_keys_str_mv AT quanjicai 12nitromethyl14deoxyandrographolide
AT chenjing 12nitromethyl14deoxyandrographolide
AT xuhao 12nitromethyl14deoxyandrographolide
AT huchenhui 12nitromethyl14deoxyandrographolide
AT wangjintang 12nitromethyl14deoxyandrographolide

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