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Di-μ-oxido-bis{[(R,R)-(+)-1-amino-2-(3-methoxy-2-oxidobenzylideneamino-κ(2) O (2),N)-1,2-diphenylethane-κN]oxidovanadium(V)} dihydrate
In the crystal structure of the title compound, [V(2)(C(22)H(21)N(2)O(2))(2)O(4)]·2H(2)O, oxide-bridged dimers of the complex are linked to water molecules by hydrogen-bonding interactions. The two five-membered chelate rings in the dimeric molecule both adopt twist conformations. Each V(V) atom...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961776/ https://www.ncbi.nlm.nih.gov/pubmed/21202755 http://dx.doi.org/10.1107/S1600536808014396 |
Sumario: | In the crystal structure of the title compound, [V(2)(C(22)H(21)N(2)O(2))(2)O(4)]·2H(2)O, oxide-bridged dimers of the complex are linked to water molecules by hydrogen-bonding interactions. The two five-membered chelate rings in the dimeric molecule both adopt twist conformations. Each V(V) atom is six-coordinated by one oxide group and by two N and one O atom of the tridentate Schiff base ligand, and is bridged by two additional oxide atoms. The metal centre has a distorted octahedral coordination. The monoanionic ligands occupy one equatorial and two axial positions. |
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