Di-μ-oxido-bis­{[(R,R)-(+)-1-amino-2-(3-methoxy-2-oxidobenzyl­ideneamino-κ(2) O (2),N)-1,2-diphenyl­ethane-κN]oxidovanadium(V)} dihydrate

In the crystal structure of the title compound, [V(2)(C(22)H(21)N(2)O(2))(2)O(4)]·2H(2)O, oxide-bridged dimers of the complex are linked to water mol­ecules by hydrogen-bonding inter­actions. The two five-membered chelate rings in the dimeric mol­ecule both adopt twist conformations. Each V(V) atom...

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Detalles Bibliográficos
Autores principales: Romanowski, Grzegorz, Lis, Tadeusz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961776/
https://www.ncbi.nlm.nih.gov/pubmed/21202755
http://dx.doi.org/10.1107/S1600536808014396
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author Romanowski, Grzegorz
Lis, Tadeusz
author_facet Romanowski, Grzegorz
Lis, Tadeusz
author_sort Romanowski, Grzegorz
collection PubMed
description In the crystal structure of the title compound, [V(2)(C(22)H(21)N(2)O(2))(2)O(4)]·2H(2)O, oxide-bridged dimers of the complex are linked to water mol­ecules by hydrogen-bonding inter­actions. The two five-membered chelate rings in the dimeric mol­ecule both adopt twist conformations. Each V(V) atom is six-coordinated by one oxide group and by two N and one O atom of the tridentate Schiff base ligand, and is bridged by two additional oxide atoms. The metal centre has a distorted octa­hedral coordination. The monoanionic ligands occupy one equatorial and two axial positions.
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spelling pubmed-29617762010-12-30 Di-μ-oxido-bis­{[(R,R)-(+)-1-amino-2-(3-methoxy-2-oxidobenzyl­ideneamino-κ(2) O (2),N)-1,2-diphenyl­ethane-κN]oxidovanadium(V)} dihydrate Romanowski, Grzegorz Lis, Tadeusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [V(2)(C(22)H(21)N(2)O(2))(2)O(4)]·2H(2)O, oxide-bridged dimers of the complex are linked to water mol­ecules by hydrogen-bonding inter­actions. The two five-membered chelate rings in the dimeric mol­ecule both adopt twist conformations. Each V(V) atom is six-coordinated by one oxide group and by two N and one O atom of the tridentate Schiff base ligand, and is bridged by two additional oxide atoms. The metal centre has a distorted octa­hedral coordination. The monoanionic ligands occupy one equatorial and two axial positions. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961776/ /pubmed/21202755 http://dx.doi.org/10.1107/S1600536808014396 Text en © Romanowski and Lis 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Romanowski, Grzegorz
Lis, Tadeusz
Di-μ-oxido-bis­{[(R,R)-(+)-1-amino-2-(3-methoxy-2-oxidobenzyl­ideneamino-κ(2) O (2),N)-1,2-diphenyl­ethane-κN]oxidovanadium(V)} dihydrate
title Di-μ-oxido-bis­{[(R,R)-(+)-1-amino-2-(3-methoxy-2-oxidobenzyl­ideneamino-κ(2) O (2),N)-1,2-diphenyl­ethane-κN]oxidovanadium(V)} dihydrate
title_full Di-μ-oxido-bis­{[(R,R)-(+)-1-amino-2-(3-methoxy-2-oxidobenzyl­ideneamino-κ(2) O (2),N)-1,2-diphenyl­ethane-κN]oxidovanadium(V)} dihydrate
title_fullStr Di-μ-oxido-bis­{[(R,R)-(+)-1-amino-2-(3-methoxy-2-oxidobenzyl­ideneamino-κ(2) O (2),N)-1,2-diphenyl­ethane-κN]oxidovanadium(V)} dihydrate
title_full_unstemmed Di-μ-oxido-bis­{[(R,R)-(+)-1-amino-2-(3-methoxy-2-oxidobenzyl­ideneamino-κ(2) O (2),N)-1,2-diphenyl­ethane-κN]oxidovanadium(V)} dihydrate
title_short Di-μ-oxido-bis­{[(R,R)-(+)-1-amino-2-(3-methoxy-2-oxidobenzyl­ideneamino-κ(2) O (2),N)-1,2-diphenyl­ethane-κN]oxidovanadium(V)} dihydrate
title_sort di-μ-oxido-bis­{[(r,r)-(+)-1-amino-2-(3-methoxy-2-oxidobenzyl­ideneamino-κ(2) o (2),n)-1,2-diphenyl­ethane-κn]oxidovanadium(v)} dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961776/
https://www.ncbi.nlm.nih.gov/pubmed/21202755
http://dx.doi.org/10.1107/S1600536808014396
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AT listadeusz dimoxidobisrr1amino23methoxy2oxidobenzylideneaminok2o2n12diphenylethaneknoxidovanadiumvdihydrate

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