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Tetra­kis(μ-4-ethyl­benzoato-κ(2) O:O′)­bis­[(4-ethyl­benzoic acid-κO)copper(II)]

The molecule of the title compound, [Cu(2)(C(9)H(9)O(2))(4)(C(9)H(10)O(2))(2)], lies on a center of inversion. It consists of four bridging ethyl­benzoate ligands, forming a cage around two Cu atoms in a syn–syn configuration, and two monodentate ethyl­benzoic acid ligands bonded apically to the squ...

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Detalles Bibliográficos
Autores principales: Sunil, Abraham C., Bezuidenhoudt, Barend C. B., Janse van Rensburg, J. Marthinus
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961780/
https://www.ncbi.nlm.nih.gov/pubmed/21202792
http://dx.doi.org/10.1107/S1600536808015924
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author Sunil, Abraham C.
Bezuidenhoudt, Barend C. B.
Janse van Rensburg, J. Marthinus
author_facet Sunil, Abraham C.
Bezuidenhoudt, Barend C. B.
Janse van Rensburg, J. Marthinus
author_sort Sunil, Abraham C.
collection PubMed
description The molecule of the title compound, [Cu(2)(C(9)H(9)O(2))(4)(C(9)H(10)O(2))(2)], lies on a center of inversion. It consists of four bridging ethyl­benzoate ligands, forming a cage around two Cu atoms in a syn–syn configuration, and two monodentate ethyl­benzoic acid ligands bonded apically to the square-planar Cu atoms. The Cu⋯Cu distance is 2.6047 (5) Å.
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spelling pubmed-29617802010-12-30 Tetra­kis(μ-4-ethyl­benzoato-κ(2) O:O′)­bis­[(4-ethyl­benzoic acid-κO)copper(II)] Sunil, Abraham C. Bezuidenhoudt, Barend C. B. Janse van Rensburg, J. Marthinus Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The molecule of the title compound, [Cu(2)(C(9)H(9)O(2))(4)(C(9)H(10)O(2))(2)], lies on a center of inversion. It consists of four bridging ethyl­benzoate ligands, forming a cage around two Cu atoms in a syn–syn configuration, and two monodentate ethyl­benzoic acid ligands bonded apically to the square-planar Cu atoms. The Cu⋯Cu distance is 2.6047 (5) Å. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961780/ /pubmed/21202792 http://dx.doi.org/10.1107/S1600536808015924 Text en © Sunil et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sunil, Abraham C.
Bezuidenhoudt, Barend C. B.
Janse van Rensburg, J. Marthinus
Tetra­kis(μ-4-ethyl­benzoato-κ(2) O:O′)­bis­[(4-ethyl­benzoic acid-κO)copper(II)]
title Tetra­kis(μ-4-ethyl­benzoato-κ(2) O:O′)­bis­[(4-ethyl­benzoic acid-κO)copper(II)]
title_full Tetra­kis(μ-4-ethyl­benzoato-κ(2) O:O′)­bis­[(4-ethyl­benzoic acid-κO)copper(II)]
title_fullStr Tetra­kis(μ-4-ethyl­benzoato-κ(2) O:O′)­bis­[(4-ethyl­benzoic acid-κO)copper(II)]
title_full_unstemmed Tetra­kis(μ-4-ethyl­benzoato-κ(2) O:O′)­bis­[(4-ethyl­benzoic acid-κO)copper(II)]
title_short Tetra­kis(μ-4-ethyl­benzoato-κ(2) O:O′)­bis­[(4-ethyl­benzoic acid-κO)copper(II)]
title_sort tetra­kis(μ-4-ethyl­benzoato-κ(2) o:o′)­bis­[(4-ethyl­benzoic acid-κo)copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961780/
https://www.ncbi.nlm.nih.gov/pubmed/21202792
http://dx.doi.org/10.1107/S1600536808015924
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