2-Amino-N-(2-hydr­oxy-3-methoxy­benzyl­idene)aniline

In the title compound, C(14)H(14)N(2)O(2), the dihedral angle between the two benzene rings is 9.67 (10)°. Two intra­molecular O—H⋯N and N—H⋯N hydrogen bonds involving the hydr­oxy and amino groups generate S(6) and S(5) ring motifs, respectively. In the crystal structure, N—H⋯O hydrogen bonds link...

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Autores principales: Al-Douh, Mohammed H., Hamid, Shafida A., Osman, Hasnah, Kia, Reza, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961787/
https://www.ncbi.nlm.nih.gov/pubmed/21202842
http://dx.doi.org/10.1107/S1600536808016292
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author Al-Douh, Mohammed H.
Hamid, Shafida A.
Osman, Hasnah
Kia, Reza
Fun, Hoong-Kun
author_facet Al-Douh, Mohammed H.
Hamid, Shafida A.
Osman, Hasnah
Kia, Reza
Fun, Hoong-Kun
author_sort Al-Douh, Mohammed H.
collection PubMed
description In the title compound, C(14)H(14)N(2)O(2), the dihedral angle between the two benzene rings is 9.67 (10)°. Two intra­molecular O—H⋯N and N—H⋯N hydrogen bonds involving the hydr­oxy and amino groups generate S(6) and S(5) ring motifs, respectively. In the crystal structure, N—H⋯O hydrogen bonds link neighboring mol­ecules. Mol­ecules are also stacked in a head-to-tail fashion along the c axis through π–π inter­actions [centroid–centroid separation of 3.7357 (12) Å] and are further linked by weak inter­molecular C—H⋯π inter­actions, giving a zigzag arrangement along the b axis.
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spelling pubmed-29617872010-12-30 2-Amino-N-(2-hydr­oxy-3-methoxy­benzyl­idene)aniline Al-Douh, Mohammed H. Hamid, Shafida A. Osman, Hasnah Kia, Reza Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(14)N(2)O(2), the dihedral angle between the two benzene rings is 9.67 (10)°. Two intra­molecular O—H⋯N and N—H⋯N hydrogen bonds involving the hydr­oxy and amino groups generate S(6) and S(5) ring motifs, respectively. In the crystal structure, N—H⋯O hydrogen bonds link neighboring mol­ecules. Mol­ecules are also stacked in a head-to-tail fashion along the c axis through π–π inter­actions [centroid–centroid separation of 3.7357 (12) Å] and are further linked by weak inter­molecular C—H⋯π inter­actions, giving a zigzag arrangement along the b axis. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961787/ /pubmed/21202842 http://dx.doi.org/10.1107/S1600536808016292 Text en © Al-Douh et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Al-Douh, Mohammed H.
Hamid, Shafida A.
Osman, Hasnah
Kia, Reza
Fun, Hoong-Kun
2-Amino-N-(2-hydr­oxy-3-methoxy­benzyl­idene)aniline
title 2-Amino-N-(2-hydr­oxy-3-methoxy­benzyl­idene)aniline
title_full 2-Amino-N-(2-hydr­oxy-3-methoxy­benzyl­idene)aniline
title_fullStr 2-Amino-N-(2-hydr­oxy-3-methoxy­benzyl­idene)aniline
title_full_unstemmed 2-Amino-N-(2-hydr­oxy-3-methoxy­benzyl­idene)aniline
title_short 2-Amino-N-(2-hydr­oxy-3-methoxy­benzyl­idene)aniline
title_sort 2-amino-n-(2-hydr­oxy-3-methoxy­benzyl­idene)aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961787/
https://www.ncbi.nlm.nih.gov/pubmed/21202842
http://dx.doi.org/10.1107/S1600536808016292
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AT hamidshafidaa 2aminon2hydroxy3methoxybenzylideneaniline
AT osmanhasnah 2aminon2hydroxy3methoxybenzylideneaniline
AT kiareza 2aminon2hydroxy3methoxybenzylideneaniline
AT funhoongkun 2aminon2hydroxy3methoxybenzylideneaniline

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