1-(2-Methyl­benzo­yl)-3-m-tolyl­thio­urea

The molecule of the title compound, C(16)H(16)N(2)OS, is not planar; the two aromatic rings are inclined to one another by 37.59 (9)°. There are intra­molecular hydrogen bonds between the benzoyl O atom and the H atom of the thio­amide N atom, and between the thio­urea S atom and the H atom of the t...

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Detalles Bibliográficos
Autores principales: Yamin, B. M., Yousuf, S., Yusof, M. S. M., Zakaria, T. N. D. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961788/
https://www.ncbi.nlm.nih.gov/pubmed/21202864
http://dx.doi.org/10.1107/S1600536808012300
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author Yamin, B. M.
Yousuf, S.
Yusof, M. S. M.
Zakaria, T. N. D. T.
author_facet Yamin, B. M.
Yousuf, S.
Yusof, M. S. M.
Zakaria, T. N. D. T.
author_sort Yamin, B. M.
collection PubMed
description The molecule of the title compound, C(16)H(16)N(2)OS, is not planar; the two aromatic rings are inclined to one another by 37.59 (9)°. There are intra­molecular hydrogen bonds between the benzoyl O atom and the H atom of the thio­amide N atom, and between the thio­urea S atom and the H atom of the tolyl group. These hydrogen bonds stabilize the mol­ecule in such a way that the thio­urea group adopts a trans–cis geometry. In the crystal structure, mol­ecules are linked by N—H⋯S inter­molecular hydrogen bonds, forming centrosymmetric dimers.
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spelling pubmed-29617882010-12-30 1-(2-Methyl­benzo­yl)-3-m-tolyl­thio­urea Yamin, B. M. Yousuf, S. Yusof, M. S. M. Zakaria, T. N. D. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title compound, C(16)H(16)N(2)OS, is not planar; the two aromatic rings are inclined to one another by 37.59 (9)°. There are intra­molecular hydrogen bonds between the benzoyl O atom and the H atom of the thio­amide N atom, and between the thio­urea S atom and the H atom of the tolyl group. These hydrogen bonds stabilize the mol­ecule in such a way that the thio­urea group adopts a trans–cis geometry. In the crystal structure, mol­ecules are linked by N—H⋯S inter­molecular hydrogen bonds, forming centrosymmetric dimers. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961788/ /pubmed/21202864 http://dx.doi.org/10.1107/S1600536808012300 Text en © Yamin et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yamin, B. M.
Yousuf, S.
Yusof, M. S. M.
Zakaria, T. N. D. T.
1-(2-Methyl­benzo­yl)-3-m-tolyl­thio­urea
title 1-(2-Methyl­benzo­yl)-3-m-tolyl­thio­urea
title_full 1-(2-Methyl­benzo­yl)-3-m-tolyl­thio­urea
title_fullStr 1-(2-Methyl­benzo­yl)-3-m-tolyl­thio­urea
title_full_unstemmed 1-(2-Methyl­benzo­yl)-3-m-tolyl­thio­urea
title_short 1-(2-Methyl­benzo­yl)-3-m-tolyl­thio­urea
title_sort 1-(2-methyl­benzo­yl)-3-m-tolyl­thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961788/
https://www.ncbi.nlm.nih.gov/pubmed/21202864
http://dx.doi.org/10.1107/S1600536808012300
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AT zakariatndt 12methylbenzoyl3mtolylthiourea

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