Diaqua­{2,6-bis­[N-(2-pyridinylmeth­yl)­carbamo­yl]­phenolato-κ(2) O (1),O (2)}zinc(II)

In the title compound, [Zn(C(20)H(17)N(4)O(3))(2)(H(2)O)(2)], the Zn(II) atom, lying on a twofold rotation axis, is six-coordinated in a distorted octa­hedral geometry by two phenolate O atoms and two carbonyl O atoms from two 2,6-bis­[(pyridin-2-ylmeth­yl)­carbamo­yl]phenolate ligands and by two wa...

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Autores principales: Suksai, Chomchai, Watchasit, Sarayut, Tuntulani, Thawatchai, Pakawatchai, Chaveng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961791/
https://www.ncbi.nlm.nih.gov/pubmed/21202754
http://dx.doi.org/10.1107/S1600536808016693
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author Suksai, Chomchai
Watchasit, Sarayut
Tuntulani, Thawatchai
Pakawatchai, Chaveng
author_facet Suksai, Chomchai
Watchasit, Sarayut
Tuntulani, Thawatchai
Pakawatchai, Chaveng
author_sort Suksai, Chomchai
collection PubMed
description In the title compound, [Zn(C(20)H(17)N(4)O(3))(2)(H(2)O)(2)], the Zn(II) atom, lying on a twofold rotation axis, is six-coordinated in a distorted octa­hedral geometry by two phenolate O atoms and two carbonyl O atoms from two 2,6-bis­[(pyridin-2-ylmeth­yl)­carbamo­yl]phenolate ligands and by two water mol­ecules. A three-dimensional network is built up from an extensive array of hydrogen bonds and π–π inter­actions between the pyridyl rings, with a centroid–centroid distance of 3.666 (3) Å.
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spelling pubmed-29617912010-12-30 Diaqua­{2,6-bis­[N-(2-pyridinylmeth­yl)­carbamo­yl]­phenolato-κ(2) O (1),O (2)}zinc(II) Suksai, Chomchai Watchasit, Sarayut Tuntulani, Thawatchai Pakawatchai, Chaveng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(20)H(17)N(4)O(3))(2)(H(2)O)(2)], the Zn(II) atom, lying on a twofold rotation axis, is six-coordinated in a distorted octa­hedral geometry by two phenolate O atoms and two carbonyl O atoms from two 2,6-bis­[(pyridin-2-ylmeth­yl)­carbamo­yl]phenolate ligands and by two water mol­ecules. A three-dimensional network is built up from an extensive array of hydrogen bonds and π–π inter­actions between the pyridyl rings, with a centroid–centroid distance of 3.666 (3) Å. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961791/ /pubmed/21202754 http://dx.doi.org/10.1107/S1600536808016693 Text en © Suksai et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Suksai, Chomchai
Watchasit, Sarayut
Tuntulani, Thawatchai
Pakawatchai, Chaveng
Diaqua­{2,6-bis­[N-(2-pyridinylmeth­yl)­carbamo­yl]­phenolato-κ(2) O (1),O (2)}zinc(II)
title Diaqua­{2,6-bis­[N-(2-pyridinylmeth­yl)­carbamo­yl]­phenolato-κ(2) O (1),O (2)}zinc(II)
title_full Diaqua­{2,6-bis­[N-(2-pyridinylmeth­yl)­carbamo­yl]­phenolato-κ(2) O (1),O (2)}zinc(II)
title_fullStr Diaqua­{2,6-bis­[N-(2-pyridinylmeth­yl)­carbamo­yl]­phenolato-κ(2) O (1),O (2)}zinc(II)
title_full_unstemmed Diaqua­{2,6-bis­[N-(2-pyridinylmeth­yl)­carbamo­yl]­phenolato-κ(2) O (1),O (2)}zinc(II)
title_short Diaqua­{2,6-bis­[N-(2-pyridinylmeth­yl)­carbamo­yl]­phenolato-κ(2) O (1),O (2)}zinc(II)
title_sort diaqua­{2,6-bis­[n-(2-pyridinylmeth­yl)­carbamo­yl]­phenolato-κ(2) o (1),o (2)}zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961791/
https://www.ncbi.nlm.nih.gov/pubmed/21202754
http://dx.doi.org/10.1107/S1600536808016693
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AT tuntulanithawatchai diaqua26bisn2pyridinylmethylcarbamoylphenolatok2o1o2zincii
AT pakawatchaichaveng diaqua26bisn2pyridinylmethylcarbamoylphenolatok2o1o2zincii

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