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Poly[[triaquatri-μ(5)-tartrato-dilanthanum(III)] dihydrate]
In the title polymer, {[La(2)(C(4)H(4)O(6))(3)(H(2)O)(3)]·2H(2)O}(n), two symmetry-independent La(III) ions are nine-coordinated and display a distorted monocapped square-antiprismatic geometry. One is coordinated by seven O atoms from four tartrate ligands and two water molecules, the other by ei...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961792/ https://www.ncbi.nlm.nih.gov/pubmed/21202787 http://dx.doi.org/10.1107/S160053680801756X |
Sumario: | In the title polymer, {[La(2)(C(4)H(4)O(6))(3)(H(2)O)(3)]·2H(2)O}(n), two symmetry-independent La(III) ions are nine-coordinated and display a distorted monocapped square-antiprismatic geometry. One is coordinated by seven O atoms from four tartrate ligands and two water molecules, the other by eight O atoms from five tartrate ligands and one water molecule. The three tartrate ligands in the asymmetric unit act identically as μ(5)-ligands, which link lanthanum centres to form a three-dimensional coordination framework. An extensive network of hydrogen bonds is observed in the crystal structure, involving two uncoordinated water molecules, one of which is disordered over two positions, with occupancies of 0.550 (13) and 0.450 (13). |
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