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Poly[[triaqua­tri-μ(5)-tartrato-dilanthanum(III)] dihydrate]

In the title polymer, {[La(2)(C(4)H(4)O(6))(3)(H(2)O)(3)]·2H(2)O}(n), two symmetry-independent La(III) ions are nine-coordinated and display a distorted monocapped square-anti­prismatic geometry. One is coordinated by seven O atoms from four tartrate ligands and two water mol­ecules, the other by ei...

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Detalles Bibliográficos
Autor principal: Shi-Zhu, Liu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961792/
https://www.ncbi.nlm.nih.gov/pubmed/21202787
http://dx.doi.org/10.1107/S160053680801756X
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author Shi-Zhu, Liu
author_facet Shi-Zhu, Liu
author_sort Shi-Zhu, Liu
collection PubMed
description In the title polymer, {[La(2)(C(4)H(4)O(6))(3)(H(2)O)(3)]·2H(2)O}(n), two symmetry-independent La(III) ions are nine-coordinated and display a distorted monocapped square-anti­prismatic geometry. One is coordinated by seven O atoms from four tartrate ligands and two water mol­ecules, the other by eight O atoms from five tartrate ligands and one water mol­ecule. The three tartrate ligands in the asymmetric unit act identically as μ(5)-ligands, which link lanthanum centres to form a three-dimensional coordination framework. An extensive network of hydrogen bonds is observed in the crystal structure, involving two uncoordinated water mol­ecules, one of which is disordered over two positions, with occupancies of 0.550 (13) and 0.450 (13).
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spelling pubmed-29617922010-12-30 Poly[[triaqua­tri-μ(5)-tartrato-dilanthanum(III)] dihydrate] Shi-Zhu, Liu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymer, {[La(2)(C(4)H(4)O(6))(3)(H(2)O)(3)]·2H(2)O}(n), two symmetry-independent La(III) ions are nine-coordinated and display a distorted monocapped square-anti­prismatic geometry. One is coordinated by seven O atoms from four tartrate ligands and two water mol­ecules, the other by eight O atoms from five tartrate ligands and one water mol­ecule. The three tartrate ligands in the asymmetric unit act identically as μ(5)-ligands, which link lanthanum centres to form a three-dimensional coordination framework. An extensive network of hydrogen bonds is observed in the crystal structure, involving two uncoordinated water mol­ecules, one of which is disordered over two positions, with occupancies of 0.550 (13) and 0.450 (13). International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961792/ /pubmed/21202787 http://dx.doi.org/10.1107/S160053680801756X Text en © Liu Shi-Zhu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shi-Zhu, Liu
Poly[[triaqua­tri-μ(5)-tartrato-dilanthanum(III)] dihydrate]
title Poly[[triaqua­tri-μ(5)-tartrato-dilanthanum(III)] dihydrate]
title_full Poly[[triaqua­tri-μ(5)-tartrato-dilanthanum(III)] dihydrate]
title_fullStr Poly[[triaqua­tri-μ(5)-tartrato-dilanthanum(III)] dihydrate]
title_full_unstemmed Poly[[triaqua­tri-μ(5)-tartrato-dilanthanum(III)] dihydrate]
title_short Poly[[triaqua­tri-μ(5)-tartrato-dilanthanum(III)] dihydrate]
title_sort poly[[triaqua­tri-μ(5)-tartrato-dilanthanum(iii)] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961792/
https://www.ncbi.nlm.nih.gov/pubmed/21202787
http://dx.doi.org/10.1107/S160053680801756X
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