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Poly[[triaquatri-μ(5)-tartrato-dilanthanum(III)] dihydrate]
In the title polymer, {[La(2)(C(4)H(4)O(6))(3)(H(2)O)(3)]·2H(2)O}(n), two symmetry-independent La(III) ions are nine-coordinated and display a distorted monocapped square-antiprismatic geometry. One is coordinated by seven O atoms from four tartrate ligands and two water molecules, the other by ei...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961792/ https://www.ncbi.nlm.nih.gov/pubmed/21202787 http://dx.doi.org/10.1107/S160053680801756X |
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author | Shi-Zhu, Liu |
author_facet | Shi-Zhu, Liu |
author_sort | Shi-Zhu, Liu |
collection | PubMed |
description | In the title polymer, {[La(2)(C(4)H(4)O(6))(3)(H(2)O)(3)]·2H(2)O}(n), two symmetry-independent La(III) ions are nine-coordinated and display a distorted monocapped square-antiprismatic geometry. One is coordinated by seven O atoms from four tartrate ligands and two water molecules, the other by eight O atoms from five tartrate ligands and one water molecule. The three tartrate ligands in the asymmetric unit act identically as μ(5)-ligands, which link lanthanum centres to form a three-dimensional coordination framework. An extensive network of hydrogen bonds is observed in the crystal structure, involving two uncoordinated water molecules, one of which is disordered over two positions, with occupancies of 0.550 (13) and 0.450 (13). |
format | Text |
id | pubmed-2961792 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29617922010-12-30 Poly[[triaquatri-μ(5)-tartrato-dilanthanum(III)] dihydrate] Shi-Zhu, Liu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymer, {[La(2)(C(4)H(4)O(6))(3)(H(2)O)(3)]·2H(2)O}(n), two symmetry-independent La(III) ions are nine-coordinated and display a distorted monocapped square-antiprismatic geometry. One is coordinated by seven O atoms from four tartrate ligands and two water molecules, the other by eight O atoms from five tartrate ligands and one water molecule. The three tartrate ligands in the asymmetric unit act identically as μ(5)-ligands, which link lanthanum centres to form a three-dimensional coordination framework. An extensive network of hydrogen bonds is observed in the crystal structure, involving two uncoordinated water molecules, one of which is disordered over two positions, with occupancies of 0.550 (13) and 0.450 (13). International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961792/ /pubmed/21202787 http://dx.doi.org/10.1107/S160053680801756X Text en © Liu Shi-Zhu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shi-Zhu, Liu Poly[[triaquatri-μ(5)-tartrato-dilanthanum(III)] dihydrate] |
title | Poly[[triaquatri-μ(5)-tartrato-dilanthanum(III)] dihydrate] |
title_full | Poly[[triaquatri-μ(5)-tartrato-dilanthanum(III)] dihydrate] |
title_fullStr | Poly[[triaquatri-μ(5)-tartrato-dilanthanum(III)] dihydrate] |
title_full_unstemmed | Poly[[triaquatri-μ(5)-tartrato-dilanthanum(III)] dihydrate] |
title_short | Poly[[triaquatri-μ(5)-tartrato-dilanthanum(III)] dihydrate] |
title_sort | poly[[triaquatri-μ(5)-tartrato-dilanthanum(iii)] dihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961792/ https://www.ncbi.nlm.nih.gov/pubmed/21202787 http://dx.doi.org/10.1107/S160053680801756X |
work_keys_str_mv | AT shizhuliu polytriaquatrim5tartratodilanthanumiiidihydrate |