Bis(5-chloro­salicylato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)cadmium(II)

In the title complex, [Cd(C(7)H(4)ClO(3))(2)(C(12)H(8)N(2))(2)], the Cd atom is coordinated by two 5-chloro­salicylate ligands and two 1,10-phenanthroline ligands, displaying a distorted octa­hedral coordination geometry. The crystal structure is stabilized by O—H⋯O and C—H⋯O hydrogen bonds and π–π...

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Detalles Bibliográficos
Autores principales: Wen, Decai, Xie, Jing, Jiang, Xiurong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961793/
https://www.ncbi.nlm.nih.gov/pubmed/21202730
http://dx.doi.org/10.1107/S1600536808015687
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author Wen, Decai
Xie, Jing
Jiang, Xiurong
author_facet Wen, Decai
Xie, Jing
Jiang, Xiurong
author_sort Wen, Decai
collection PubMed
description In the title complex, [Cd(C(7)H(4)ClO(3))(2)(C(12)H(8)N(2))(2)], the Cd atom is coordinated by two 5-chloro­salicylate ligands and two 1,10-phenanthroline ligands, displaying a distorted octa­hedral coordination geometry. The crystal structure is stabilized by O—H⋯O and C—H⋯O hydrogen bonds and π–π inter­actions between the 1,10-phenanthroline ligands and 5-chloro­salicylate ligands, with a centroid–centroid distance between neighbouring aromatic rings of 3.730 (1) Å.
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spelling pubmed-29617932010-12-30 Bis(5-chloro­salicylato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)cadmium(II) Wen, Decai Xie, Jing Jiang, Xiurong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(C(7)H(4)ClO(3))(2)(C(12)H(8)N(2))(2)], the Cd atom is coordinated by two 5-chloro­salicylate ligands and two 1,10-phenanthroline ligands, displaying a distorted octa­hedral coordination geometry. The crystal structure is stabilized by O—H⋯O and C—H⋯O hydrogen bonds and π–π inter­actions between the 1,10-phenanthroline ligands and 5-chloro­salicylate ligands, with a centroid–centroid distance between neighbouring aromatic rings of 3.730 (1) Å. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961793/ /pubmed/21202730 http://dx.doi.org/10.1107/S1600536808015687 Text en © Wen et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wen, Decai
Xie, Jing
Jiang, Xiurong
Bis(5-chloro­salicylato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)cadmium(II)
title Bis(5-chloro­salicylato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)cadmium(II)
title_full Bis(5-chloro­salicylato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)cadmium(II)
title_fullStr Bis(5-chloro­salicylato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)cadmium(II)
title_full_unstemmed Bis(5-chloro­salicylato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)cadmium(II)
title_short Bis(5-chloro­salicylato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)cadmium(II)
title_sort bis(5-chloro­salicylato-κo)bis­(1,10-phenanthroline-κ(2) n,n′)cadmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961793/
https://www.ncbi.nlm.nih.gov/pubmed/21202730
http://dx.doi.org/10.1107/S1600536808015687
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AT xiejing bis5chlorosalicylatokobis110phenanthrolinek2nncadmiumii
AT jiangxiurong bis5chlorosalicylatokobis110phenanthrolinek2nncadmiumii

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