Bis(2-benzamido­benzimidazolato-κ(2) N (1),O)(N,N-dimethyl­formamide-κO)copper(II)

In the title compound, [Cu(C(14)H(10)N(3)O)(2)(C(3)H(7)NO)], the Cu(II) atom is five-coordinated by two N,O-bidentate 2-benzamido­benzimidazolate anions and one O-coordinated dimethyl­formamide (DMF) mol­ecule, resulting in a distorted square-based pyramidal CuN(2)O(3) geometry for the metal atom, w...

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Detalles Bibliográficos
Autores principales: Thiam, Elhadj Ibrahima, Tamboura, Farba, Gaye, Mohamed, Sall, Abdou Salam, Barry, Aliou Hamady
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961798/
https://www.ncbi.nlm.nih.gov/pubmed/21202747
http://dx.doi.org/10.1107/S1600536808016383
Descripción
Sumario:In the title compound, [Cu(C(14)H(10)N(3)O)(2)(C(3)H(7)NO)], the Cu(II) atom is five-coordinated by two N,O-bidentate 2-benzamido­benzimidazolate anions and one O-coordinated dimethyl­formamide (DMF) mol­ecule, resulting in a distorted square-based pyramidal CuN(2)O(3) geometry for the metal atom, with the DMF O atom at the apical site. In the crystal structure, inter­molecular N—H⋯N hydrogen bonds result in chains of mol­ecules propagating along [100].

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