Bis(2-benzamido­benzimidazolato-κ(2) N (1),O)(N,N-dimethyl­formamide-κO)copper(II)

In the title compound, [Cu(C(14)H(10)N(3)O)(2)(C(3)H(7)NO)], the Cu(II) atom is five-coordinated by two N,O-bidentate 2-benzamido­benzimidazolate anions and one O-coordinated dimethyl­formamide (DMF) mol­ecule, resulting in a distorted square-based pyramidal CuN(2)O(3) geometry for the metal atom, w...

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Autores principales: Thiam, Elhadj Ibrahima, Tamboura, Farba, Gaye, Mohamed, Sall, Abdou Salam, Barry, Aliou Hamady
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961798/
https://www.ncbi.nlm.nih.gov/pubmed/21202747
http://dx.doi.org/10.1107/S1600536808016383
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author Thiam, Elhadj Ibrahima
Tamboura, Farba
Gaye, Mohamed
Sall, Abdou Salam
Barry, Aliou Hamady
author_facet Thiam, Elhadj Ibrahima
Tamboura, Farba
Gaye, Mohamed
Sall, Abdou Salam
Barry, Aliou Hamady
author_sort Thiam, Elhadj Ibrahima
collection PubMed
description In the title compound, [Cu(C(14)H(10)N(3)O)(2)(C(3)H(7)NO)], the Cu(II) atom is five-coordinated by two N,O-bidentate 2-benzamido­benzimidazolate anions and one O-coordinated dimethyl­formamide (DMF) mol­ecule, resulting in a distorted square-based pyramidal CuN(2)O(3) geometry for the metal atom, with the DMF O atom at the apical site. In the crystal structure, inter­molecular N—H⋯N hydrogen bonds result in chains of mol­ecules propagating along [100].
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spelling pubmed-29617982010-12-30 Bis(2-benzamido­benzimidazolato-κ(2) N (1),O)(N,N-dimethyl­formamide-κO)copper(II) Thiam, Elhadj Ibrahima Tamboura, Farba Gaye, Mohamed Sall, Abdou Salam Barry, Aliou Hamady Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(14)H(10)N(3)O)(2)(C(3)H(7)NO)], the Cu(II) atom is five-coordinated by two N,O-bidentate 2-benzamido­benzimidazolate anions and one O-coordinated dimethyl­formamide (DMF) mol­ecule, resulting in a distorted square-based pyramidal CuN(2)O(3) geometry for the metal atom, with the DMF O atom at the apical site. In the crystal structure, inter­molecular N—H⋯N hydrogen bonds result in chains of mol­ecules propagating along [100]. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961798/ /pubmed/21202747 http://dx.doi.org/10.1107/S1600536808016383 Text en © Thiam et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Thiam, Elhadj Ibrahima
Tamboura, Farba
Gaye, Mohamed
Sall, Abdou Salam
Barry, Aliou Hamady
Bis(2-benzamido­benzimidazolato-κ(2) N (1),O)(N,N-dimethyl­formamide-κO)copper(II)
title Bis(2-benzamido­benzimidazolato-κ(2) N (1),O)(N,N-dimethyl­formamide-κO)copper(II)
title_full Bis(2-benzamido­benzimidazolato-κ(2) N (1),O)(N,N-dimethyl­formamide-κO)copper(II)
title_fullStr Bis(2-benzamido­benzimidazolato-κ(2) N (1),O)(N,N-dimethyl­formamide-κO)copper(II)
title_full_unstemmed Bis(2-benzamido­benzimidazolato-κ(2) N (1),O)(N,N-dimethyl­formamide-κO)copper(II)
title_short Bis(2-benzamido­benzimidazolato-κ(2) N (1),O)(N,N-dimethyl­formamide-κO)copper(II)
title_sort bis(2-benzamido­benzimidazolato-κ(2) n (1),o)(n,n-dimethyl­formamide-κo)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961798/
https://www.ncbi.nlm.nih.gov/pubmed/21202747
http://dx.doi.org/10.1107/S1600536808016383
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AT gayemohamed bis2benzamidobenzimidazolatok2n1onndimethylformamidekocopperii
AT sallabdousalam bis2benzamidobenzimidazolatok2n1onndimethylformamidekocopperii
AT barryaliouhamady bis2benzamidobenzimidazolatok2n1onndimethylformamidekocopperii

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