Penta­aqua­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))copper(II) penta­hydrate

The title compound, [Cu(C(9)H(4)N(2)O(4))(H(2)O)(5)]·5H(2)O, contains one crystallographically independent Cu(II) atom and one 1H-benzimidazole-5,6-dicarboxyl­ate (bdc) ligand, along with five coordinated and five uncoordinated water mol­ecules. The Cu(II) atom is six-coordinated by one N atom from...

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Detalles Bibliográficos
Autores principales: Gao, Qian, Gao, Wei-Hong, Zhang, Chao-Yan, Xie, Ya-Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961800/
https://www.ncbi.nlm.nih.gov/pubmed/21202783
http://dx.doi.org/10.1107/S1600536808017595
Descripción
Sumario:The title compound, [Cu(C(9)H(4)N(2)O(4))(H(2)O)(5)]·5H(2)O, contains one crystallographically independent Cu(II) atom and one 1H-benzimidazole-5,6-dicarboxyl­ate (bdc) ligand, along with five coordinated and five uncoordinated water mol­ecules. The Cu(II) atom is six-coordinated by one N atom from the bdc ligand and five O atoms from water mol­ecules, giving an octa­hedral coordination geometry. Hydrogen bonds link the mononuclear complex and uncoordinated water mol­ecules into a three-dimensional network.

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