Penta­aqua­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))copper(II) penta­hydrate

The title compound, [Cu(C(9)H(4)N(2)O(4))(H(2)O)(5)]·5H(2)O, contains one crystallographically independent Cu(II) atom and one 1H-benzimidazole-5,6-dicarboxyl­ate (bdc) ligand, along with five coordinated and five uncoordinated water mol­ecules. The Cu(II) atom is six-coordinated by one N atom from...

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Detalles Bibliográficos
Autores principales: Gao, Qian, Gao, Wei-Hong, Zhang, Chao-Yan, Xie, Ya-Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961800/
https://www.ncbi.nlm.nih.gov/pubmed/21202783
http://dx.doi.org/10.1107/S1600536808017595
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author Gao, Qian
Gao, Wei-Hong
Zhang, Chao-Yan
Xie, Ya-Bo
author_facet Gao, Qian
Gao, Wei-Hong
Zhang, Chao-Yan
Xie, Ya-Bo
author_sort Gao, Qian
collection PubMed
description The title compound, [Cu(C(9)H(4)N(2)O(4))(H(2)O)(5)]·5H(2)O, contains one crystallographically independent Cu(II) atom and one 1H-benzimidazole-5,6-dicarboxyl­ate (bdc) ligand, along with five coordinated and five uncoordinated water mol­ecules. The Cu(II) atom is six-coordinated by one N atom from the bdc ligand and five O atoms from water mol­ecules, giving an octa­hedral coordination geometry. Hydrogen bonds link the mononuclear complex and uncoordinated water mol­ecules into a three-dimensional network.
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spelling pubmed-29618002010-12-30 Penta­aqua­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))copper(II) penta­hydrate Gao, Qian Gao, Wei-Hong Zhang, Chao-Yan Xie, Ya-Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(9)H(4)N(2)O(4))(H(2)O)(5)]·5H(2)O, contains one crystallographically independent Cu(II) atom and one 1H-benzimidazole-5,6-dicarboxyl­ate (bdc) ligand, along with five coordinated and five uncoordinated water mol­ecules. The Cu(II) atom is six-coordinated by one N atom from the bdc ligand and five O atoms from water mol­ecules, giving an octa­hedral coordination geometry. Hydrogen bonds link the mononuclear complex and uncoordinated water mol­ecules into a three-dimensional network. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961800/ /pubmed/21202783 http://dx.doi.org/10.1107/S1600536808017595 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Gao, Qian
Gao, Wei-Hong
Zhang, Chao-Yan
Xie, Ya-Bo
Penta­aqua­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))copper(II) penta­hydrate
title Penta­aqua­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))copper(II) penta­hydrate
title_full Penta­aqua­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))copper(II) penta­hydrate
title_fullStr Penta­aqua­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))copper(II) penta­hydrate
title_full_unstemmed Penta­aqua­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))copper(II) penta­hydrate
title_short Penta­aqua­(1H-benzimidazole-5,6-di­carboxyl­ato-κN (3))copper(II) penta­hydrate
title_sort penta­aqua­(1h-benzimidazole-5,6-di­carboxyl­ato-κn (3))copper(ii) penta­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961800/
https://www.ncbi.nlm.nih.gov/pubmed/21202783
http://dx.doi.org/10.1107/S1600536808017595
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