Hexakis(dimethyl sulfoxide-κO)chromium(III) trichloride

In the title compound, [Cr(C(2)H(6)OS)(6)]Cl(3), each Cr(III) ion is located on a three-fold inversion axis and is coordinated by six dimethyl­sulfoxide ligands [Cr—O = 1.970 (2)–1.972 (2) Å; O—Cr—O = 88.19 (9) and 91.81 (9)°] in a slightly distorted octa­hedral geometry. The Cl(−) anions take part...

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Autores principales: Mikhaylichenko, Yuliya M., Haukka, Matti, Pavlenko, Vadim O., Fritsky, Igor O., Iskenderov, Turganbay S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961805/
https://www.ncbi.nlm.nih.gov/pubmed/21202768
http://dx.doi.org/10.1107/S1600536808016784
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author Mikhaylichenko, Yuliya M.
Haukka, Matti
Pavlenko, Vadim O.
Fritsky, Igor O.
Iskenderov, Turganbay S.
author_facet Mikhaylichenko, Yuliya M.
Haukka, Matti
Pavlenko, Vadim O.
Fritsky, Igor O.
Iskenderov, Turganbay S.
author_sort Mikhaylichenko, Yuliya M.
collection PubMed
description In the title compound, [Cr(C(2)H(6)OS)(6)]Cl(3), each Cr(III) ion is located on a three-fold inversion axis and is coordinated by six dimethyl­sulfoxide ligands [Cr—O = 1.970 (2)–1.972 (2) Å; O—Cr—O = 88.19 (9) and 91.81 (9)°] in a slightly distorted octa­hedral geometry. The Cl(−) anions take part in the formation of weak C—H⋯Cl hydrogen bonds, which contribute to the crystal packing stabilization.
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spelling pubmed-29618052010-12-30 Hexakis(dimethyl sulfoxide-κO)chromium(III) trichloride Mikhaylichenko, Yuliya M. Haukka, Matti Pavlenko, Vadim O. Fritsky, Igor O. Iskenderov, Turganbay S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cr(C(2)H(6)OS)(6)]Cl(3), each Cr(III) ion is located on a three-fold inversion axis and is coordinated by six dimethyl­sulfoxide ligands [Cr—O = 1.970 (2)–1.972 (2) Å; O—Cr—O = 88.19 (9) and 91.81 (9)°] in a slightly distorted octa­hedral geometry. The Cl(−) anions take part in the formation of weak C—H⋯Cl hydrogen bonds, which contribute to the crystal packing stabilization. International Union of Crystallography 2008-06-13 /pmc/articles/PMC2961805/ /pubmed/21202768 http://dx.doi.org/10.1107/S1600536808016784 Text en © Mikhaylichenko et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mikhaylichenko, Yuliya M.
Haukka, Matti
Pavlenko, Vadim O.
Fritsky, Igor O.
Iskenderov, Turganbay S.
Hexakis(dimethyl sulfoxide-κO)chromium(III) trichloride
title Hexakis(dimethyl sulfoxide-κO)chromium(III) trichloride
title_full Hexakis(dimethyl sulfoxide-κO)chromium(III) trichloride
title_fullStr Hexakis(dimethyl sulfoxide-κO)chromium(III) trichloride
title_full_unstemmed Hexakis(dimethyl sulfoxide-κO)chromium(III) trichloride
title_short Hexakis(dimethyl sulfoxide-κO)chromium(III) trichloride
title_sort hexakis(dimethyl sulfoxide-κo)chromium(iii) trichloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961805/
https://www.ncbi.nlm.nih.gov/pubmed/21202768
http://dx.doi.org/10.1107/S1600536808016784
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AT haukkamatti hexakisdimethylsulfoxidekochromiumiiitrichloride
AT pavlenkovadimo hexakisdimethylsulfoxidekochromiumiiitrichloride
AT fritskyigoro hexakisdimethylsulfoxidekochromiumiiitrichloride
AT iskenderovturganbays hexakisdimethylsulfoxidekochromiumiiitrichloride

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