Swietenolide monohydrate

The title compound, a natural b,d-seco-limonoid, C(27)H(34)O(8)·H(2)O, and known as Swietenolide monohydrate, has been isolated from S. macrophylla King. In the molecular structure, the four fused six-membered rings adopt twist-boat (ring A), approximate chair (ring B), envelope (ring C) and half-ch...

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Detalles Bibliográficos
Autores principales: Tan, Seok-Keik, Osman, Hasnah, Wong, Keng-Chong, Fun, Hoong-Kun, Chantrapromma, Suchada
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961806/
https://www.ncbi.nlm.nih.gov/pubmed/21202901
http://dx.doi.org/10.1107/S1600536808017431
Descripción
Sumario:The title compound, a natural b,d-seco-limonoid, C(27)H(34)O(8)·H(2)O, and known as Swietenolide monohydrate, has been isolated from S. macrophylla King. In the molecular structure, the four fused six-membered rings adopt twist-boat (ring A), approximate chair (ring B), envelope (ring C) and half-chair (ring D) conformations. The attached furan ring is essentially planar. O—H⋯O hydrogen bonds and weak C—H⋯O inter­actions connect the mol­ecules into a two-dimensional network parallel to the (100) plane. C—H⋯π inter­actions are also observed.

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