Swietenolide monohydrate

The title compound, a natural b,d-seco-limonoid, C(27)H(34)O(8)·H(2)O, and known as Swietenolide monohydrate, has been isolated from S. macrophylla King. In the molecular structure, the four fused six-membered rings adopt twist-boat (ring A), approximate chair (ring B), envelope (ring C) and half-ch...

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Autores principales: Tan, Seok-Keik, Osman, Hasnah, Wong, Keng-Chong, Fun, Hoong-Kun, Chantrapromma, Suchada
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961806/
https://www.ncbi.nlm.nih.gov/pubmed/21202901
http://dx.doi.org/10.1107/S1600536808017431
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author Tan, Seok-Keik
Osman, Hasnah
Wong, Keng-Chong
Fun, Hoong-Kun
Chantrapromma, Suchada
author_facet Tan, Seok-Keik
Osman, Hasnah
Wong, Keng-Chong
Fun, Hoong-Kun
Chantrapromma, Suchada
author_sort Tan, Seok-Keik
collection PubMed
description The title compound, a natural b,d-seco-limonoid, C(27)H(34)O(8)·H(2)O, and known as Swietenolide monohydrate, has been isolated from S. macrophylla King. In the molecular structure, the four fused six-membered rings adopt twist-boat (ring A), approximate chair (ring B), envelope (ring C) and half-chair (ring D) conformations. The attached furan ring is essentially planar. O—H⋯O hydrogen bonds and weak C—H⋯O inter­actions connect the mol­ecules into a two-dimensional network parallel to the (100) plane. C—H⋯π inter­actions are also observed.
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spelling pubmed-29618062010-12-30 Swietenolide monohydrate Tan, Seok-Keik Osman, Hasnah Wong, Keng-Chong Fun, Hoong-Kun Chantrapromma, Suchada Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, a natural b,d-seco-limonoid, C(27)H(34)O(8)·H(2)O, and known as Swietenolide monohydrate, has been isolated from S. macrophylla King. In the molecular structure, the four fused six-membered rings adopt twist-boat (ring A), approximate chair (ring B), envelope (ring C) and half-chair (ring D) conformations. The attached furan ring is essentially planar. O—H⋯O hydrogen bonds and weak C—H⋯O inter­actions connect the mol­ecules into a two-dimensional network parallel to the (100) plane. C—H⋯π inter­actions are also observed. International Union of Crystallography 2008-06-13 /pmc/articles/PMC2961806/ /pubmed/21202901 http://dx.doi.org/10.1107/S1600536808017431 Text en © Tan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tan, Seok-Keik
Osman, Hasnah
Wong, Keng-Chong
Fun, Hoong-Kun
Chantrapromma, Suchada
Swietenolide monohydrate
title Swietenolide monohydrate
title_full Swietenolide monohydrate
title_fullStr Swietenolide monohydrate
title_full_unstemmed Swietenolide monohydrate
title_short Swietenolide monohydrate
title_sort swietenolide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961806/
https://www.ncbi.nlm.nih.gov/pubmed/21202901
http://dx.doi.org/10.1107/S1600536808017431
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AT osmanhasnah swietenolidemonohydrate
AT wongkengchong swietenolidemonohydrate
AT funhoongkun swietenolidemonohydrate
AT chantraprommasuchada swietenolidemonohydrate

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