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3,9-Dibromo-5,7-dihydrodibenzo[c,e]oxepine
The title compound, C(14)H(10)Br(2)O, is a biphenyl derivative containing a –CH(2)—O—CH(2)– bridge in the 2,2′-position. The compound displays a twisted conformation with the two benzene rings making a dihedral angle of 45.02 (5)°, while the central seven-membered ring is in a boat conformation. The...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961808/ https://www.ncbi.nlm.nih.gov/pubmed/21202933 http://dx.doi.org/10.1107/S1600536808018175 |
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author | Zhang, Hai-Quan Bao-Li, Yang, Guang-Di Ma, Yu-Guang |
author_facet | Zhang, Hai-Quan Bao-Li, Yang, Guang-Di Ma, Yu-Guang |
author_sort | Zhang, Hai-Quan |
collection | PubMed |
description | The title compound, C(14)H(10)Br(2)O, is a biphenyl derivative containing a –CH(2)—O—CH(2)– bridge in the 2,2′-position. The compound displays a twisted conformation with the two benzene rings making a dihedral angle of 45.02 (5)°, while the central seven-membered ring is in a boat conformation. The molecule lies on a crystallographic twofold axis of symmetry passing through the O atom and bisecting the 1,1′ C—C bond. |
format | Text |
id | pubmed-2961808 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29618082010-12-30 3,9-Dibromo-5,7-dihydrodibenzo[c,e]oxepine Zhang, Hai-Quan Bao-Li, Yang, Guang-Di Ma, Yu-Guang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(10)Br(2)O, is a biphenyl derivative containing a –CH(2)—O—CH(2)– bridge in the 2,2′-position. The compound displays a twisted conformation with the two benzene rings making a dihedral angle of 45.02 (5)°, while the central seven-membered ring is in a boat conformation. The molecule lies on a crystallographic twofold axis of symmetry passing through the O atom and bisecting the 1,1′ C—C bond. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961808/ /pubmed/21202933 http://dx.doi.org/10.1107/S1600536808018175 Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Zhang, Hai-Quan Bao-Li, Yang, Guang-Di Ma, Yu-Guang 3,9-Dibromo-5,7-dihydrodibenzo[c,e]oxepine |
title | 3,9-Dibromo-5,7-dihydrodibenzo[c,e]oxepine |
title_full | 3,9-Dibromo-5,7-dihydrodibenzo[c,e]oxepine |
title_fullStr | 3,9-Dibromo-5,7-dihydrodibenzo[c,e]oxepine |
title_full_unstemmed | 3,9-Dibromo-5,7-dihydrodibenzo[c,e]oxepine |
title_short | 3,9-Dibromo-5,7-dihydrodibenzo[c,e]oxepine |
title_sort | 3,9-dibromo-5,7-dihydrodibenzo[c,e]oxepine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961808/ https://www.ncbi.nlm.nih.gov/pubmed/21202933 http://dx.doi.org/10.1107/S1600536808018175 |
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