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3,9-Dibromo-5,7-dihydro­dibenzo[c,e]oxepine

The title compound, C(14)H(10)Br(2)O, is a biphenyl derivative containing a –CH(2)—O—CH(2)– bridge in the 2,2′-position. The compound displays a twisted conformation with the two benzene rings making a dihedral angle of 45.02 (5)°, while the central seven-membered ring is in a boat conformation. The...

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Detalles Bibliográficos
Autores principales: Zhang, Hai-Quan, Bao-Li, Yang, Guang-Di, Ma, Yu-Guang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961808/
https://www.ncbi.nlm.nih.gov/pubmed/21202933
http://dx.doi.org/10.1107/S1600536808018175
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author Zhang, Hai-Quan
Bao-Li,
Yang, Guang-Di
Ma, Yu-Guang
author_facet Zhang, Hai-Quan
Bao-Li,
Yang, Guang-Di
Ma, Yu-Guang
author_sort Zhang, Hai-Quan
collection PubMed
description The title compound, C(14)H(10)Br(2)O, is a biphenyl derivative containing a –CH(2)—O—CH(2)– bridge in the 2,2′-position. The compound displays a twisted conformation with the two benzene rings making a dihedral angle of 45.02 (5)°, while the central seven-membered ring is in a boat conformation. The mol­ecule lies on a crystallographic twofold axis of symmetry passing through the O atom and bis­ecting the 1,1′ C—C bond.
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spelling pubmed-29618082010-12-30 3,9-Dibromo-5,7-dihydro­dibenzo[c,e]oxepine Zhang, Hai-Quan Bao-Li, Yang, Guang-Di Ma, Yu-Guang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(10)Br(2)O, is a biphenyl derivative containing a –CH(2)—O—CH(2)– bridge in the 2,2′-position. The compound displays a twisted conformation with the two benzene rings making a dihedral angle of 45.02 (5)°, while the central seven-membered ring is in a boat conformation. The mol­ecule lies on a crystallographic twofold axis of symmetry passing through the O atom and bis­ecting the 1,1′ C—C bond. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961808/ /pubmed/21202933 http://dx.doi.org/10.1107/S1600536808018175 Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Hai-Quan
Bao-Li,
Yang, Guang-Di
Ma, Yu-Guang
3,9-Dibromo-5,7-dihydro­dibenzo[c,e]oxepine
title 3,9-Dibromo-5,7-dihydro­dibenzo[c,e]oxepine
title_full 3,9-Dibromo-5,7-dihydro­dibenzo[c,e]oxepine
title_fullStr 3,9-Dibromo-5,7-dihydro­dibenzo[c,e]oxepine
title_full_unstemmed 3,9-Dibromo-5,7-dihydro­dibenzo[c,e]oxepine
title_short 3,9-Dibromo-5,7-dihydro­dibenzo[c,e]oxepine
title_sort 3,9-dibromo-5,7-dihydro­dibenzo[c,e]oxepine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961808/
https://www.ncbi.nlm.nih.gov/pubmed/21202933
http://dx.doi.org/10.1107/S1600536808018175
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