Bis(1-{bis­[2-(diphenyl­phosphino­yl)eth­yl]phosphan­yl}-2-(diphenyl­phosphan­yl)ethane)dinitratoplatinum(II) methanol tetra­solvate

In the title compound, [Pt(NO(3))(2)(C(42)H(42)O(2)P(4))(2)]·4CH(3)OH, the Pt atom positioned on a crystallographic centre of inversion. The two symmetry-equivalent nitrate anions are weakly coordinated to the Pt(II) ion, creating, together with four P ligand atoms, a distorted octa­hedral coordinat...

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Detalles Bibliográficos
Autores principales: Rieckborn, Timo Paul, Karakoc, Emine, Prosenc, Marc Heinrich
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961811/
https://www.ncbi.nlm.nih.gov/pubmed/21202764
http://dx.doi.org/10.1107/S160053680801533X
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author Rieckborn, Timo Paul
Karakoc, Emine
Prosenc, Marc Heinrich
author_facet Rieckborn, Timo Paul
Karakoc, Emine
Prosenc, Marc Heinrich
author_sort Rieckborn, Timo Paul
collection PubMed
description In the title compound, [Pt(NO(3))(2)(C(42)H(42)O(2)P(4))(2)]·4CH(3)OH, the Pt atom positioned on a crystallographic centre of inversion. The two symmetry-equivalent nitrate anions are weakly coordinated to the Pt(II) ion, creating, together with four P ligand atoms, a distorted octa­hedral coordination environment. In addition, several close C—H⋯O contacts between the nitrate O atoms and phenyl H atoms are found. Hydrogen bonds from two methanol solvent mol­ecules to one of the O—P groups complete the crystal structure.
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spelling pubmed-29618112010-12-30 Bis(1-{bis­[2-(diphenyl­phosphino­yl)eth­yl]phosphan­yl}-2-(diphenyl­phosphan­yl)ethane)dinitratoplatinum(II) methanol tetra­solvate Rieckborn, Timo Paul Karakoc, Emine Prosenc, Marc Heinrich Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pt(NO(3))(2)(C(42)H(42)O(2)P(4))(2)]·4CH(3)OH, the Pt atom positioned on a crystallographic centre of inversion. The two symmetry-equivalent nitrate anions are weakly coordinated to the Pt(II) ion, creating, together with four P ligand atoms, a distorted octa­hedral coordination environment. In addition, several close C—H⋯O contacts between the nitrate O atoms and phenyl H atoms are found. Hydrogen bonds from two methanol solvent mol­ecules to one of the O—P groups complete the crystal structure. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961811/ /pubmed/21202764 http://dx.doi.org/10.1107/S160053680801533X Text en © Rieckborn et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rieckborn, Timo Paul
Karakoc, Emine
Prosenc, Marc Heinrich
Bis(1-{bis­[2-(diphenyl­phosphino­yl)eth­yl]phosphan­yl}-2-(diphenyl­phosphan­yl)ethane)dinitratoplatinum(II) methanol tetra­solvate
title Bis(1-{bis­[2-(diphenyl­phosphino­yl)eth­yl]phosphan­yl}-2-(diphenyl­phosphan­yl)ethane)dinitratoplatinum(II) methanol tetra­solvate
title_full Bis(1-{bis­[2-(diphenyl­phosphino­yl)eth­yl]phosphan­yl}-2-(diphenyl­phosphan­yl)ethane)dinitratoplatinum(II) methanol tetra­solvate
title_fullStr Bis(1-{bis­[2-(diphenyl­phosphino­yl)eth­yl]phosphan­yl}-2-(diphenyl­phosphan­yl)ethane)dinitratoplatinum(II) methanol tetra­solvate
title_full_unstemmed Bis(1-{bis­[2-(diphenyl­phosphino­yl)eth­yl]phosphan­yl}-2-(diphenyl­phosphan­yl)ethane)dinitratoplatinum(II) methanol tetra­solvate
title_short Bis(1-{bis­[2-(diphenyl­phosphino­yl)eth­yl]phosphan­yl}-2-(diphenyl­phosphan­yl)ethane)dinitratoplatinum(II) methanol tetra­solvate
title_sort bis(1-{bis­[2-(diphenyl­phosphino­yl)eth­yl]phosphan­yl}-2-(diphenyl­phosphan­yl)ethane)dinitratoplatinum(ii) methanol tetra­solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961811/
https://www.ncbi.nlm.nih.gov/pubmed/21202764
http://dx.doi.org/10.1107/S160053680801533X
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AT karakocemine bis1bis2diphenylphosphinoylethylphosphanyl2diphenylphosphanylethanedinitratoplatinumiimethanoltetrasolvate
AT prosencmarcheinrich bis1bis2diphenylphosphinoylethylphosphanyl2diphenylphosphanylethanedinitratoplatinumiimethanoltetrasolvate

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