(1R,2R,5R,6S,9R,10S,13S,14S,18R)-1,6,7,8,9,14,15,16,17,17,18-Undeca­chloro­penta­cyclo­[12.2.1.1(6,9).0(2,13).0(5,10)]octa­deca-7,15-diene

The title compound, C(18)H(13)Cl(11), is an undecachlorinated commercial flame retardant. The asymmetric unit contains two independent half-mol­ecules. The complete mol­ecules are generated by crystallographic inversion symmetry, causing the terminal H atoms and one of the Cl atoms to be disordered...

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Detalles Bibliográficos
Autores principales: Riddell, Nicole, McCrindle, Robert, Arsenault, Gilles, Lough, Alan J
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961815/
https://www.ncbi.nlm.nih.gov/pubmed/21202884
http://dx.doi.org/10.1107/S160053680801622X
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author Riddell, Nicole
McCrindle, Robert
Arsenault, Gilles
Lough, Alan J
author_facet Riddell, Nicole
McCrindle, Robert
Arsenault, Gilles
Lough, Alan J
author_sort Riddell, Nicole
collection PubMed
description The title compound, C(18)H(13)Cl(11), is an undecachlorinated commercial flame retardant. The asymmetric unit contains two independent half-mol­ecules. The complete mol­ecules are generated by crystallographic inversion symmetry, causing the terminal H atoms and one of the Cl atoms to be disordered equally over two sites in each mol­ecule. The central eight-membered rings are in chair-type conformations. In the crystal structure, there is a single weak inter­molecular C—H⋯Cl hydrogen bond.
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spelling pubmed-29618152010-12-30 (1R,2R,5R,6S,9R,10S,13S,14S,18R)-1,6,7,8,9,14,15,16,17,17,18-Undeca­chloro­penta­cyclo­[12.2.1.1(6,9).0(2,13).0(5,10)]octa­deca-7,15-diene Riddell, Nicole McCrindle, Robert Arsenault, Gilles Lough, Alan J Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(13)Cl(11), is an undecachlorinated commercial flame retardant. The asymmetric unit contains two independent half-mol­ecules. The complete mol­ecules are generated by crystallographic inversion symmetry, causing the terminal H atoms and one of the Cl atoms to be disordered equally over two sites in each mol­ecule. The central eight-membered rings are in chair-type conformations. In the crystal structure, there is a single weak inter­molecular C—H⋯Cl hydrogen bond. International Union of Crystallography 2008-06-13 /pmc/articles/PMC2961815/ /pubmed/21202884 http://dx.doi.org/10.1107/S160053680801622X Text en © Riddell et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Riddell, Nicole
McCrindle, Robert
Arsenault, Gilles
Lough, Alan J
(1R,2R,5R,6S,9R,10S,13S,14S,18R)-1,6,7,8,9,14,15,16,17,17,18-Undeca­chloro­penta­cyclo­[12.2.1.1(6,9).0(2,13).0(5,10)]octa­deca-7,15-diene
title (1R,2R,5R,6S,9R,10S,13S,14S,18R)-1,6,7,8,9,14,15,16,17,17,18-Undeca­chloro­penta­cyclo­[12.2.1.1(6,9).0(2,13).0(5,10)]octa­deca-7,15-diene
title_full (1R,2R,5R,6S,9R,10S,13S,14S,18R)-1,6,7,8,9,14,15,16,17,17,18-Undeca­chloro­penta­cyclo­[12.2.1.1(6,9).0(2,13).0(5,10)]octa­deca-7,15-diene
title_fullStr (1R,2R,5R,6S,9R,10S,13S,14S,18R)-1,6,7,8,9,14,15,16,17,17,18-Undeca­chloro­penta­cyclo­[12.2.1.1(6,9).0(2,13).0(5,10)]octa­deca-7,15-diene
title_full_unstemmed (1R,2R,5R,6S,9R,10S,13S,14S,18R)-1,6,7,8,9,14,15,16,17,17,18-Undeca­chloro­penta­cyclo­[12.2.1.1(6,9).0(2,13).0(5,10)]octa­deca-7,15-diene
title_short (1R,2R,5R,6S,9R,10S,13S,14S,18R)-1,6,7,8,9,14,15,16,17,17,18-Undeca­chloro­penta­cyclo­[12.2.1.1(6,9).0(2,13).0(5,10)]octa­deca-7,15-diene
title_sort (1r,2r,5r,6s,9r,10s,13s,14s,18r)-1,6,7,8,9,14,15,16,17,17,18-undeca­chloro­penta­cyclo­[12.2.1.1(6,9).0(2,13).0(5,10)]octa­deca-7,15-diene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961815/
https://www.ncbi.nlm.nih.gov/pubmed/21202884
http://dx.doi.org/10.1107/S160053680801622X
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