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{Bis[4-(2-pyridyl)pyrimidin-2-yl] sulfide}dibromidocobalt(II)
The title compound, [CoBr(2)(C(18)H(12)N(6)S)], is a mononuclear complex in which a twofold rotation axis passes through the Co and S atoms. The Co(II) center is six-coordinated by four N atoms from one bis[4-(2-pyridyl)pyrimidin-2-yl] sulfide (L) ligand and two bromide anions, forming an octahed...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961816/ https://www.ncbi.nlm.nih.gov/pubmed/21202733 http://dx.doi.org/10.1107/S1600536808015821 |
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author | Li, Cai-Yun Tong, Xiao-Lan Hu, Tong-Liang |
author_facet | Li, Cai-Yun Tong, Xiao-Lan Hu, Tong-Liang |
author_sort | Li, Cai-Yun |
collection | PubMed |
description | The title compound, [CoBr(2)(C(18)H(12)N(6)S)], is a mononuclear complex in which a twofold rotation axis passes through the Co and S atoms. The Co(II) center is six-coordinated by four N atoms from one bis[4-(2-pyridyl)pyrimidin-2-yl] sulfide (L) ligand and two bromide anions, forming an octahedral coordination geometry, where the four donor N atoms are located in the equatorial plane and the Br atoms occupy the axial positions. The sum of the bond angles around the Co atom in the equatorial plane is 360.5°, with the four N atoms and the central Co atom almost coplanar. In the crystal structure, the mononuclear units are linked by π–π stacking interactions (the interplanar distances are 3.469 and 3.533 Å, and the corresponding centroid–centroid distances are 3.791 and 3.896 Å) into a three-dimensional supramolecular network. |
format | Text |
id | pubmed-2961816 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29618162010-12-30 {Bis[4-(2-pyridyl)pyrimidin-2-yl] sulfide}dibromidocobalt(II) Li, Cai-Yun Tong, Xiao-Lan Hu, Tong-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [CoBr(2)(C(18)H(12)N(6)S)], is a mononuclear complex in which a twofold rotation axis passes through the Co and S atoms. The Co(II) center is six-coordinated by four N atoms from one bis[4-(2-pyridyl)pyrimidin-2-yl] sulfide (L) ligand and two bromide anions, forming an octahedral coordination geometry, where the four donor N atoms are located in the equatorial plane and the Br atoms occupy the axial positions. The sum of the bond angles around the Co atom in the equatorial plane is 360.5°, with the four N atoms and the central Co atom almost coplanar. In the crystal structure, the mononuclear units are linked by π–π stacking interactions (the interplanar distances are 3.469 and 3.533 Å, and the corresponding centroid–centroid distances are 3.791 and 3.896 Å) into a three-dimensional supramolecular network. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961816/ /pubmed/21202733 http://dx.doi.org/10.1107/S1600536808015821 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Cai-Yun Tong, Xiao-Lan Hu, Tong-Liang {Bis[4-(2-pyridyl)pyrimidin-2-yl] sulfide}dibromidocobalt(II) |
title | {Bis[4-(2-pyridyl)pyrimidin-2-yl] sulfide}dibromidocobalt(II) |
title_full | {Bis[4-(2-pyridyl)pyrimidin-2-yl] sulfide}dibromidocobalt(II) |
title_fullStr | {Bis[4-(2-pyridyl)pyrimidin-2-yl] sulfide}dibromidocobalt(II) |
title_full_unstemmed | {Bis[4-(2-pyridyl)pyrimidin-2-yl] sulfide}dibromidocobalt(II) |
title_short | {Bis[4-(2-pyridyl)pyrimidin-2-yl] sulfide}dibromidocobalt(II) |
title_sort | {bis[4-(2-pyridyl)pyrimidin-2-yl] sulfide}dibromidocobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961816/ https://www.ncbi.nlm.nih.gov/pubmed/21202733 http://dx.doi.org/10.1107/S1600536808015821 |
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