Cargando…

{Bis[4-(2-pyrid­yl)pyrimidin-2-yl] sulfide}dibromidocobalt(II)

The title compound, [CoBr(2)(C(18)H(12)N(6)S)], is a mononuclear complex in which a twofold rotation axis passes through the Co and S atoms. The Co(II) center is six-coordinated by four N atoms from one bis­[4-(2-pyrid­yl)pyrimidin-2-yl] sulfide (L) ligand and two bromide anions, forming an octa­hed...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Cai-Yun, Tong, Xiao-Lan, Hu, Tong-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961816/
https://www.ncbi.nlm.nih.gov/pubmed/21202733
http://dx.doi.org/10.1107/S1600536808015821
_version_ 1782189073000038400
author Li, Cai-Yun
Tong, Xiao-Lan
Hu, Tong-Liang
author_facet Li, Cai-Yun
Tong, Xiao-Lan
Hu, Tong-Liang
author_sort Li, Cai-Yun
collection PubMed
description The title compound, [CoBr(2)(C(18)H(12)N(6)S)], is a mononuclear complex in which a twofold rotation axis passes through the Co and S atoms. The Co(II) center is six-coordinated by four N atoms from one bis­[4-(2-pyrid­yl)pyrimidin-2-yl] sulfide (L) ligand and two bromide anions, forming an octa­hedral coordination geometry, where the four donor N atoms are located in the equatorial plane and the Br atoms occupy the axial positions. The sum of the bond angles around the Co atom in the equatorial plane is 360.5°, with the four N atoms and the central Co atom almost coplanar. In the crystal structure, the mononuclear units are linked by π–π stacking inter­actions (the inter­planar distances are 3.469 and 3.533 Å, and the corresponding centroid–centroid distances are 3.791 and 3.896 Å) into a three-dimensional supra­molecular network.
format Text
id pubmed-2961816
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29618162010-12-30 {Bis[4-(2-pyrid­yl)pyrimidin-2-yl] sulfide}dibromidocobalt(II) Li, Cai-Yun Tong, Xiao-Lan Hu, Tong-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [CoBr(2)(C(18)H(12)N(6)S)], is a mononuclear complex in which a twofold rotation axis passes through the Co and S atoms. The Co(II) center is six-coordinated by four N atoms from one bis­[4-(2-pyrid­yl)pyrimidin-2-yl] sulfide (L) ligand and two bromide anions, forming an octa­hedral coordination geometry, where the four donor N atoms are located in the equatorial plane and the Br atoms occupy the axial positions. The sum of the bond angles around the Co atom in the equatorial plane is 360.5°, with the four N atoms and the central Co atom almost coplanar. In the crystal structure, the mononuclear units are linked by π–π stacking inter­actions (the inter­planar distances are 3.469 and 3.533 Å, and the corresponding centroid–centroid distances are 3.791 and 3.896 Å) into a three-dimensional supra­molecular network. International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961816/ /pubmed/21202733 http://dx.doi.org/10.1107/S1600536808015821 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Cai-Yun
Tong, Xiao-Lan
Hu, Tong-Liang
{Bis[4-(2-pyrid­yl)pyrimidin-2-yl] sulfide}dibromidocobalt(II)
title {Bis[4-(2-pyrid­yl)pyrimidin-2-yl] sulfide}dibromidocobalt(II)
title_full {Bis[4-(2-pyrid­yl)pyrimidin-2-yl] sulfide}dibromidocobalt(II)
title_fullStr {Bis[4-(2-pyrid­yl)pyrimidin-2-yl] sulfide}dibromidocobalt(II)
title_full_unstemmed {Bis[4-(2-pyrid­yl)pyrimidin-2-yl] sulfide}dibromidocobalt(II)
title_short {Bis[4-(2-pyrid­yl)pyrimidin-2-yl] sulfide}dibromidocobalt(II)
title_sort {bis[4-(2-pyrid­yl)pyrimidin-2-yl] sulfide}dibromidocobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961816/
https://www.ncbi.nlm.nih.gov/pubmed/21202733
http://dx.doi.org/10.1107/S1600536808015821
work_keys_str_mv AT licaiyun bis42pyridylpyrimidin2ylsulfidedibromidocobaltii
AT tongxiaolan bis42pyridylpyrimidin2ylsulfidedibromidocobaltii
AT hutongliang bis42pyridylpyrimidin2ylsulfidedibromidocobaltii