1-(4-Chloro­phen­yl)piperazine-1,4-diium tetra­chlorido­zincate(II) monohydrate

In the crystal structure of the title compound, (C(10)H(15)ClN(2))[ZnCl(4)]·H(2)O, the Zn atom is coordinated by four Cl atoms in a tetrahedral geometry. The water mol­ecules and the 1-(4-chloro­phen­yl)piperazine-1,4-diium cations inter­act with the [ZnCl(4)](2−) anions through O—H⋯Cl, N—H⋯Cl, N—H⋯...

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Autores principales: Ben Gharbia, Imen, Kefi, Riadh, El Glaoui, Meher, Jeanneau, Erwann, Ben Nasr, Cherif
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961817/
https://www.ncbi.nlm.nih.gov/pubmed/21202751
http://dx.doi.org/10.1107/S1600536808016590
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author Ben Gharbia, Imen
Kefi, Riadh
El Glaoui, Meher
Jeanneau, Erwann
Ben Nasr, Cherif
author_facet Ben Gharbia, Imen
Kefi, Riadh
El Glaoui, Meher
Jeanneau, Erwann
Ben Nasr, Cherif
author_sort Ben Gharbia, Imen
collection PubMed
description In the crystal structure of the title compound, (C(10)H(15)ClN(2))[ZnCl(4)]·H(2)O, the Zn atom is coordinated by four Cl atoms in a tetrahedral geometry. The water mol­ecules and the 1-(4-chloro­phen­yl)piperazine-1,4-diium cations inter­act with the [ZnCl(4)](2−) anions through O—H⋯Cl, N—H⋯Cl, N—H⋯O and C—H⋯Cl hydrogen bonds (five simple and one bifurcated). Inter­molecular π–π stacking inter­actions are present between adjacent aromatic rings of 1-(4-chloro­phenyl)­piperazine-1,4-diium cations (the centroid–centroid distance is 3.453 Å).
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spelling pubmed-29618172010-12-30 1-(4-Chloro­phen­yl)piperazine-1,4-diium tetra­chlorido­zincate(II) monohydrate Ben Gharbia, Imen Kefi, Riadh El Glaoui, Meher Jeanneau, Erwann Ben Nasr, Cherif Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, (C(10)H(15)ClN(2))[ZnCl(4)]·H(2)O, the Zn atom is coordinated by four Cl atoms in a tetrahedral geometry. The water mol­ecules and the 1-(4-chloro­phen­yl)piperazine-1,4-diium cations inter­act with the [ZnCl(4)](2−) anions through O—H⋯Cl, N—H⋯Cl, N—H⋯O and C—H⋯Cl hydrogen bonds (five simple and one bifurcated). Inter­molecular π–π stacking inter­actions are present between adjacent aromatic rings of 1-(4-chloro­phenyl)­piperazine-1,4-diium cations (the centroid–centroid distance is 3.453 Å). International Union of Crystallography 2008-06-07 /pmc/articles/PMC2961817/ /pubmed/21202751 http://dx.doi.org/10.1107/S1600536808016590 Text en © Ben Gharbia et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ben Gharbia, Imen
Kefi, Riadh
El Glaoui, Meher
Jeanneau, Erwann
Ben Nasr, Cherif
1-(4-Chloro­phen­yl)piperazine-1,4-diium tetra­chlorido­zincate(II) monohydrate
title 1-(4-Chloro­phen­yl)piperazine-1,4-diium tetra­chlorido­zincate(II) monohydrate
title_full 1-(4-Chloro­phen­yl)piperazine-1,4-diium tetra­chlorido­zincate(II) monohydrate
title_fullStr 1-(4-Chloro­phen­yl)piperazine-1,4-diium tetra­chlorido­zincate(II) monohydrate
title_full_unstemmed 1-(4-Chloro­phen­yl)piperazine-1,4-diium tetra­chlorido­zincate(II) monohydrate
title_short 1-(4-Chloro­phen­yl)piperazine-1,4-diium tetra­chlorido­zincate(II) monohydrate
title_sort 1-(4-chloro­phen­yl)piperazine-1,4-diium tetra­chlorido­zincate(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961817/
https://www.ncbi.nlm.nih.gov/pubmed/21202751
http://dx.doi.org/10.1107/S1600536808016590
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