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Diethyl[N-(3-methoxy-2-oxidobenzylidene)-N′-(oxidomethylene)hydrazine-κ(3) O,N,O′]tin(IV)
In the molecule of the title compound, [Sn(C(2)H(5))(2)(C(9)H(8)N(2)O(3))], the Sn atom is five-coordinated in a distorted trigonal-bipyramidal configuration by two O and one N atoms of the tridentate Schiff base ligand in the equatorial plane, and by two C atoms of ethyl groups in the axial positi...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961818/ https://www.ncbi.nlm.nih.gov/pubmed/21202810 http://dx.doi.org/10.1107/S1600536808018953 |
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author | Shuja, Shaukat Tahir, M. Nawaz Ali, Saqib Khalid, Nasir |
author_facet | Shuja, Shaukat Tahir, M. Nawaz Ali, Saqib Khalid, Nasir |
author_sort | Shuja, Shaukat |
collection | PubMed |
description | In the molecule of the title compound, [Sn(C(2)H(5))(2)(C(9)H(8)N(2)O(3))], the Sn atom is five-coordinated in a distorted trigonal-bipyramidal configuration by two O and one N atoms of the tridentate Schiff base ligand in the equatorial plane, and by two C atoms of ethyl groups in the axial positions. In the crystal structure, intermolecular C—H⋯O hydrogen bonds link the molecules into centrosymmetric dimers. |
format | Text |
id | pubmed-2961818 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29618182010-12-30 Diethyl[N-(3-methoxy-2-oxidobenzylidene)-N′-(oxidomethylene)hydrazine-κ(3) O,N,O′]tin(IV) Shuja, Shaukat Tahir, M. Nawaz Ali, Saqib Khalid, Nasir Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the molecule of the title compound, [Sn(C(2)H(5))(2)(C(9)H(8)N(2)O(3))], the Sn atom is five-coordinated in a distorted trigonal-bipyramidal configuration by two O and one N atoms of the tridentate Schiff base ligand in the equatorial plane, and by two C atoms of ethyl groups in the axial positions. In the crystal structure, intermolecular C—H⋯O hydrogen bonds link the molecules into centrosymmetric dimers. International Union of Crystallography 2008-06-28 /pmc/articles/PMC2961818/ /pubmed/21202810 http://dx.doi.org/10.1107/S1600536808018953 Text en © Shuja et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shuja, Shaukat Tahir, M. Nawaz Ali, Saqib Khalid, Nasir Diethyl[N-(3-methoxy-2-oxidobenzylidene)-N′-(oxidomethylene)hydrazine-κ(3) O,N,O′]tin(IV) |
title | Diethyl[N-(3-methoxy-2-oxidobenzylidene)-N′-(oxidomethylene)hydrazine-κ(3)
O,N,O′]tin(IV) |
title_full | Diethyl[N-(3-methoxy-2-oxidobenzylidene)-N′-(oxidomethylene)hydrazine-κ(3)
O,N,O′]tin(IV) |
title_fullStr | Diethyl[N-(3-methoxy-2-oxidobenzylidene)-N′-(oxidomethylene)hydrazine-κ(3)
O,N,O′]tin(IV) |
title_full_unstemmed | Diethyl[N-(3-methoxy-2-oxidobenzylidene)-N′-(oxidomethylene)hydrazine-κ(3)
O,N,O′]tin(IV) |
title_short | Diethyl[N-(3-methoxy-2-oxidobenzylidene)-N′-(oxidomethylene)hydrazine-κ(3)
O,N,O′]tin(IV) |
title_sort | diethyl[n-(3-methoxy-2-oxidobenzylidene)-n′-(oxidomethylene)hydrazine-κ(3)
o,n,o′]tin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961818/ https://www.ncbi.nlm.nih.gov/pubmed/21202810 http://dx.doi.org/10.1107/S1600536808018953 |
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