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Redetermination of 2,4,6-tricyclo­hexyl-1,3,5-trioxane

The title compound, C(21)H(36)O(3), was obtained by treatment of cyclo­hexa­necarbaldehyde with catalytic toluene-4-sulfonic acid monohydrate. This redetermination results in a crystal structure with significantly higher precision than the original determination [Diana & Ganis (1963 ▶). Atti Acc...

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Detalles Bibliográficos
Autores principales: Moreno-Fuquen, Rodolfo, Rios, Eunice, Paredes, Rodrigo, Jaramillo, Luz Marina, Zukerman-Schpector, Julio
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961819/
https://www.ncbi.nlm.nih.gov/pubmed/21202930
http://dx.doi.org/10.1107/S1600536808018084
Descripción
Sumario:The title compound, C(21)H(36)O(3), was obtained by treatment of cyclo­hexa­necarbaldehyde with catalytic toluene-4-sulfonic acid monohydrate. This redetermination results in a crystal structure with significantly higher precision than the original determination [Diana & Ganis (1963 ▶). Atti Accad. Naz. Lincei, 35, 80–88]. The asymmetric unit contains one sixth of the mol­ecule, the formula unit being generated by crystallographic 3m symmetry. In the mol­ecule, the trioxane and cyclo­hexane rings are in chair conformations. In the crystal structure, mol­ecules are linked by weak C—H⋯O hydrogen bonds along the [001] direction.