Redetermination of 2,4,6-tricyclo­hexyl-1,3,5-trioxane

The title compound, C(21)H(36)O(3), was obtained by treatment of cyclo­hexa­necarbaldehyde with catalytic toluene-4-sulfonic acid monohydrate. This redetermination results in a crystal structure with significantly higher precision than the original determination [Diana & Ganis (1963 ▶). Atti Acc...

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Autores principales: Moreno-Fuquen, Rodolfo, Rios, Eunice, Paredes, Rodrigo, Jaramillo, Luz Marina, Zukerman-Schpector, Julio
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961819/
https://www.ncbi.nlm.nih.gov/pubmed/21202930
http://dx.doi.org/10.1107/S1600536808018084
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author Moreno-Fuquen, Rodolfo
Rios, Eunice
Paredes, Rodrigo
Jaramillo, Luz Marina
Zukerman-Schpector, Julio
author_facet Moreno-Fuquen, Rodolfo
Rios, Eunice
Paredes, Rodrigo
Jaramillo, Luz Marina
Zukerman-Schpector, Julio
author_sort Moreno-Fuquen, Rodolfo
collection PubMed
description The title compound, C(21)H(36)O(3), was obtained by treatment of cyclo­hexa­necarbaldehyde with catalytic toluene-4-sulfonic acid monohydrate. This redetermination results in a crystal structure with significantly higher precision than the original determination [Diana & Ganis (1963 ▶). Atti Accad. Naz. Lincei, 35, 80–88]. The asymmetric unit contains one sixth of the mol­ecule, the formula unit being generated by crystallographic 3m symmetry. In the mol­ecule, the trioxane and cyclo­hexane rings are in chair conformations. In the crystal structure, mol­ecules are linked by weak C—H⋯O hydrogen bonds along the [001] direction.
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spelling pubmed-29618192010-12-30 Redetermination of 2,4,6-tricyclo­hexyl-1,3,5-trioxane Moreno-Fuquen, Rodolfo Rios, Eunice Paredes, Rodrigo Jaramillo, Luz Marina Zukerman-Schpector, Julio Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(36)O(3), was obtained by treatment of cyclo­hexa­necarbaldehyde with catalytic toluene-4-sulfonic acid monohydrate. This redetermination results in a crystal structure with significantly higher precision than the original determination [Diana & Ganis (1963 ▶). Atti Accad. Naz. Lincei, 35, 80–88]. The asymmetric unit contains one sixth of the mol­ecule, the formula unit being generated by crystallographic 3m symmetry. In the mol­ecule, the trioxane and cyclo­hexane rings are in chair conformations. In the crystal structure, mol­ecules are linked by weak C—H⋯O hydrogen bonds along the [001] direction. International Union of Crystallography 2008-06-19 /pmc/articles/PMC2961819/ /pubmed/21202930 http://dx.doi.org/10.1107/S1600536808018084 Text en © Moreno-Fuquen et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Moreno-Fuquen, Rodolfo
Rios, Eunice
Paredes, Rodrigo
Jaramillo, Luz Marina
Zukerman-Schpector, Julio
Redetermination of 2,4,6-tricyclo­hexyl-1,3,5-trioxane
title Redetermination of 2,4,6-tricyclo­hexyl-1,3,5-trioxane
title_full Redetermination of 2,4,6-tricyclo­hexyl-1,3,5-trioxane
title_fullStr Redetermination of 2,4,6-tricyclo­hexyl-1,3,5-trioxane
title_full_unstemmed Redetermination of 2,4,6-tricyclo­hexyl-1,3,5-trioxane
title_short Redetermination of 2,4,6-tricyclo­hexyl-1,3,5-trioxane
title_sort redetermination of 2,4,6-tricyclo­hexyl-1,3,5-trioxane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961819/
https://www.ncbi.nlm.nih.gov/pubmed/21202930
http://dx.doi.org/10.1107/S1600536808018084
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